23451-78-7

Basic information

• Product Name: 1,2,2-trifluorovinyl phenyl sulfide
• Synonyms: 1,2,2-trifluorovinyl phenyl sulfide
• CAS NO: 23451-78-7
• Molecular Weight: 190.189
• Mol File: 23451-78-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,2,2-trifluorovinyl phenyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,2-trifluorovinyl phenyl sulfide(23451-78-7)
• EPA Substance Registry System: 1,2,2-trifluorovinyl phenyl sulfide(23451-78-7)

Safety Data

• Hazardous Substances Data: 23451-78-7(Hazardous Substances Data)

Upstream product

• 23451-79-8 [(1,2-dichloro-1,2,2-trifluoroethyl)thio]benzene 
• 79-38-9 Chlorotrifluoroethylene 
• 931-59-9 benzenesulfenyl chloride 
• 811-97-2 1,1,1,2-tetrafluoroethane 
• 3541-14-8 phenyl toluene-4-thiosulfonate 
• 75-77-4 chloro-trimethyl-silane 
• 403-58-7 1,1,2,2-tetrafluoroethyl phenyl sulfide 
• 4111-54-0 lithium diisopropyl amide 

Downstream Products

• 102688-16-4 2,3,3-trifluoro-2-phenylthio-1-tert-butylthio-1-cyanocyclobutane 
• 23451-79-8 [(1,2-dichloro-1,2,2-trifluoroethyl)thio]benzene 
• 709668-91-7 1,1,2-trifluoro-1-oxolan-2-yl-2-(phenylsulfanyl)ethane 
• 709668-98-4 1,2,2-trifluoro-3-methyl-1-phenylsulfanylbutane 
• 709668-97-3 1,2,2-trifluoro-1-phenylsulfanylundecane 
• 709668-99-5 1-cyclohexyl-1,1,2-trifluoro-2-phenylsulfanylethane 
• 23451-81-2 phenyl trifluorovinyl sulfone 
• 709668-94-0 3,3,4-trifluoro-2,2-dimethyl-4-phenylsulfanylbutane 
• 709668-96-2 1,2,2-trifluoro-1-phenylsulfanyloctane 
• 709669-04-5 (1,2,2-trifluoro-3-methyl-butane-1-sulfinyl)-benzene 
• 709669-01-2 (1,2,2-trifluoro-pentane-1-sulfinyl)-benzene 
• 709669-00-1 (1,2,2-trifluoro-3,3-dimethyl-butane-1-sulfinyl)-benzene 
• 709669-13-6 S-phenyl 2,2-difluoro-2-(oxolan-2-yl)ethanethioate 
• 709669-06-7 2-(2-benzenesulfinyl-1,1,2-trifluoro-ethyl)-tetrahydro-furan 

Relevant articles and documents

Synthesis of Fluoroalkyl Sulfides via Additive-Free Hydrothiolation and Sequential Functionalization Reactions

A modular synthetic method, involving a hydrothiolation, silylation, and fluoroalkylation, for the construction of highly functionalized fluoroalkyl sulfides has been developed. The use of aprotic polar solvents enables the additive-free chemoselective hydrothiolation of tetrafluoroethylene, trifluorochloroethylene, and hexafluoropropene with various thiols. The stepwise functionalization reactions convert the hydrothiolated intermediates into the tetrafluoroethyl sulfides in high efficiency. The method avoids the use of the environmental pollutant Halon-2402, which was employed as a building block in a reported synthetic route.

SYNTHESIS OF FLUORINATED VINYL SULFIDES AND SELENIDES

The reaction between fluoroolefins 1 and 10e and benzenesulfenyl or selenenyl halides 6 is found to be solvent-dependent and gives in most cases predominantly the regioisomer 8.The structure of adducts 8 and 9 are ascertained by 1H, 19F and 77Se NMR spectroscopy.Compounds 8 are easily halogenated and treatment of the products with magnesium or zinc leads to the desired polyfluorovinyl sulfides and selenides 10.A second route of synthesis of these reagents results from the reaction of fluorovinyllithio-derivatives 11 with benzenesulfenyl or selenenyl halides.Olefin 10e is also obtained from the selenoacetal 8t of trifluoroacetaldehyde.