24173-36-2Relevant articles and documents
Influence of the substituent D/A at the 1,2,3-triazole ring on novel terpyridine derivatives: Synthesis and properties
Zych, Dawid,Slodek, Aneta,Zimny, D?astin,Golba, Sylwia,Malarz, Katarzyna,Mrozek-Wilczkiewicz, Anna
, p. 16554 - 16564 (2019)
In this study, we newly designed and developed a synthesis route based on the 1,3-dipolar cycloaddition of the derivatives of 4′-(1,2,3-triazol-4-yl)phenyl-2,2′:6′,2′′-terpyridine with various (hetero)aryl substituents, differing in electronic character, on a triazol ring. The obtained compounds were comprehensively characterized by UV-Vis spectroscopy and electrochemical and thermal studies. Moreover, preliminary biological tests were conducted. The investigation allowed the selection of materials with the most promising properties with particular emphasis on the nature of the substituents. In addition, theoretical studies (DFT and TD-DFT) were performed to verify the comprehensive understanding of experimental results.
One-pot synthesis of biopolymeric hollow nanospheres by photocrosslinking
Yin, Yihua,Xu, Sha,Chang, Dan,Zheng, Hua,Li, Junli,Liu, Xiaoping,Xu, Peihu,Xiong, Fuliang
, p. 8222 - 8224 (2010)
Biopolymeric hollow nanospheres with stabilized structure have been prepared by self-assembly of amphiphatic photocrosslinkable carboxymethyl chitosans in a water medium into hollow nanocapsules and subsequent in situ photo-crosslinking of the photoreactive functional groups in the shells of the nanocapsules.
An examination of the utility of photogenerated reagents by using α chymotrypsin
Bridges,Knowles
, p. 663 - 668 (1974)
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In vivo targeted delivery of antibodies into cancer cells with pH-responsive cell-penetrating poly(disulfide)s
Dai, Xiaoyang,Kong, Yulong,Liao, Jia-Yu,Qian, Linghui,Shao, Jinning,Wang, Wenchao,Weng, Qinjie,Yan, Jiaqi,Yao, Shao Q.,Zeng, Kui,Zeng, Su,Zhang, Ying
supporting information, p. 1314 - 1317 (2022/02/05)
Cell-penetrating poly(disulfide)s (CPDs) are promising vehicles for cytosolic delivery of proteins. However, currently available arginine-rich CPD has rarely been reported for systemic delivery due to its "always"positive charge. Herein, we developed pH-r
Photoredox-Catalyzed Four-Component Reaction for the Synthesis of Complex Secondary Amines
Kammer, Lisa Marie,Krumb, Matthias,Spitzbarth, Benjamin,Lipp, Benjamin,Kühlborn, Jonas,Busold, Jonas,Mulina, Olga M.,Terentev, Alexander O.,Opatz, Till
supporting information, p. 3318 - 3322 (2020/03/24)
The one-pot sulfonylation/aminoalkylation of styrene derivatives furnishing substituted ?3-sulfonylamines was accomplished through a photoredox-catalyzed four-component reaction. Besides one molecule of water and the sodium counterion of the sulfinate, all atoms of the starting materials are transferred to the final product, rendering this process highly atom-efficient. The operationally simple protocol allows for the simultaneous formation of three new single bonds (C-S, C-N, and C-C) and therefore grants rapid access to structurally diverse products.