25559-56-2Relevant articles and documents
Unique features of chiral palladium enolates derived from β-ketoamide: structure and catalytic asymmetric Michael and fluorination reactions
Hayamizu, Kenji,Terayama, Naoki,Hashizume, Daisuke,Dodo, Kosuke,Sodeoka, Mikiko
, p. 6594 - 6601 (2015)
Abstract We have previously reported enantioselective reactions of 1,3-diketones and β-ketoesters with various electrophiles catalyzed by chiral Pd complex, in which chiral Pd enolates play a key role. Here, we present a detailed examination of Pd-catalyz
Enantioselective α-hydroxylation of -ketoamides
De Fusco, Claudia,Meninno, Sara,Tedesco, Consiglia,Lattanzi, Alessandra
supporting information, p. 896 - 899 (2013/02/26)
The first enantioselective α-hydroxylation reaction of α-substituted -ketoamides has been developed by using the commercially available hydroquinine/TBHP system. The tertiary alcohols are obtained in good to high yield and up to 83% ee, which can be improved by a single crystallization.
A NEW METHOD FOR SYNTHESIS OF N-ARYL-2-BENZOYLPROPIONAMIDES
Sychev, D. I.
, p. 1205 - 1206 (2007/10/02)
-