26826-81-3

Basic information

• Product Name: Benzenemethanesulfenyl chloride
• CAS NO: 26826-81-3
• Molecular Formula: C7H7ClS
• Molecular Weight: 158.652
• Mol File: 26826-81-3.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Benzenemethanesulfenyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanesulfenyl chloride(26826-81-3)
• EPA Substance Registry System: Benzenemethanesulfenyl chloride(26826-81-3)

Safety Data

• Hazardous Substances Data: 26826-81-3(Hazardous Substances Data)

Upstream product

• 150-60-7 dibenzyl disulphide 
• 32362-99-5 benzylthioacetate 
• 3878-41-9 2-(benzylthio)ethanol 
• 100-53-8 phenylmethanethiol 
• 128-09-6 N-chloro-succinimide 

Downstream Products

• 3970-13-6 benzyl chloromethyl sulfide 
• 4332-51-8 1-(benzylthio)-2-chloroethane 
• 25310-03-6 Benzyl-<α-benzoylimino-benzyl>-disulfid 
• 28194-62-9 2-benzylsulfanyl-2-chloro-1,2-diphenyl-ethanone 
• 33663-80-8 1-benzyl-2-(tert-butyl)disulfane 
• 150-60-7 dibenzyl disulphide 
• 911460-64-5 benzyl 1,1,1,3,3,3-hexafluoropropan-2-yl sulfide 
• 91735-95-4 Z-2-Benzylthio-3-phenylpropenanilide 
• 1340481-84-6 C₁₆H₂₁NO₃S 
• 68794-93-4 dodecyl phenylmethyl disulfide 
• 14204-26-3 N-(benzylthio)phthalimide 
• 109475-80-1 S-benzyl-S-(2-chloro-ethyl)-N-(toluene-4-sulfonyl)-sulfimide 
• 66998-67-2 2-benzylsulfonylethyl chloride 
• 126361-23-7 Sodium; 17,18-bis-(2-benzylsulfanyl-2-methyl-propylamino)-octadecanoate 

Relevant articles and documents

Synthesis of Enhanced, Isolable Disulfanium Salts and their Application to Thiiranium-Promoted Polyene Cyclizations

Although electrophile-promoted polyene cyclizations have long been a mainstay transformation for the rapid and stereocontrolled preparation of varied natural products and designed molecules, efforts to effect sulfur-promoted variants have arguably lagged behind other counterparts. This state of affairs is particularly true with alkyl sulfide-based electrophiles, even in racemic variants. Herein, building on previously reported discoveries, is described a distinct and modular method to prepare a range of isolable alkyl and aryl disulfanium salts that can affect thiiranium-based polyene cyclizations in moderate to good yields. In most of the substrates probed, these reagents provide superior yields to previously reported alternatives. In addition, initial efforts to develop an asymmetric variant of the process through the use of chiral versions of these reagents are discussed.

Trichloroisocyanuric acid-promoted thiolation of phosphites by thiols

A simple and convenient method for the synthesis of thiophosphates by coupling of phosphites with thiols under mild conditions has been developed. The reactions were promoted by trichloroisocyanuric acid (TCCA) and were carried out at room temperature in

Controlled chemical release of hydrogen sulfide

Agents of formula: where R1 and R2 vary independently and are acyl, sulfonyl, phosphoryl, alkyl, substituted alkyl, halogen, aryl, arylalkyl, substituted aryl, heteroaryl, alkenyl, substituted alkenyl, alkynyl, substituted alkynyl, cycloalkyl, heterocycle, or heteroatoms; and R3 is H or a member of a ring structure which includes R2, are provided; as are agents of formula: where R1, R2 and R3 vary independently and: R1=OH, OR′, NHR′, NR′R″ (with R′ R″=alkyl, aryl, heteroaryl, etc); R2=acyl, alkyl, aryl, sulfonyl, etc; R3=alkyl, aryl, substituted aryl, heteroaryl, etc; and R4 and R5 are (independently) H, methyl or alkyl, substituted alkyl, aryl, substituted aryl, etc. Methods of using the agents to treat e.g. cardiovascular disease, stroke, shock, injuries caused by hypoxia, male erectile dysfunction, and Alzheimer's are provided.