26978-16-5

Basic information

• Product Name: Peroxide, methyl 1-methyl-1-phenylethyl
• CAS NO: 26978-16-5
• Molecular Formula: C10H14O2
• Molecular Weight: 166.22
• Mol File: 26978-16-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Peroxide, methyl 1-methyl-1-phenylethyl(CAS DataBase Reference)
• NIST Chemistry Reference: Peroxide, methyl 1-methyl-1-phenylethyl(26978-16-5)
• EPA Substance Registry System: Peroxide, methyl 1-methyl-1-phenylethyl(26978-16-5)

Safety Data

• Hazardous Substances Data: 26978-16-5(Hazardous Substances Data)

Upstream product

• 80-15-9 Cumene hydroperoxide 
• 74-88-4 methyl iodide 
• 77-78-1 dimethyl sulfate 

Downstream Products

• 617-94-7 1-methyl-1-phenylethyl alcohol 
• 98-86-2 acetophenone 
• 38868-78-9 2,2-dimethoxy-1-phenylpropan-1-one 
• 6956-56-5 2,2-dimethoxy-1-phenylethanone 

Relevant articles and documents

Rapid, One-Step Synthesis of α-Ketoacetals via Electrophilic Etherification

Herein, we report a rapid, one-step synthesis of α-ketoacetals via electrophilic etherification of α-alkoxy enolates and monoperoxyacetals. Methyl, primary, and secondary α-ketoacetals were obtained in 44-63% yields from tetrahydropyranyl substrates; usin

Selectivity in Lewis acid-mediated fragmentations of peroxides and ozonides: Application to the synthesis of alkenes, homoallyl ethers, and 1,2-dioxolanes

Fragmentation of dialkyl peroxides and ozonides is strongly influenced by the choice of Lewis acid. TiCl4 promotes C-O ionization (SN1 reaction) of tertiary peroxides while SnCl4 and BF3·OEt2 promote O-O heterolysis (Hock reaction). The cationic intermediates are trapped with allyltrimethylsilane to afford allylated alkanes and homoallyl ethers. In the absence of a nucleophile, ozonides (1,2,4-trioxolanes) invariably undergo O-O heterolysis. However, the combination of allyltrimethylsilane and SnCl4 results in formation of 1,2-dioxolanes via trapping of intermediates derived from SN1 ionization.