2743-00-2

Basic information

• Product Name: Benzenamine, 4-methoxy-N-(1-phenylethylidene)-
• CAS NO: 2743-00-2
• Molecular Formula: C15H15NO
• Molecular Weight: 225.29
• Mol File: 2743-00-2.mol
• Article Data: 118

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-methoxy-N-(1-phenylethylidene)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-methoxy-N-(1-phenylethylidene)-(2743-00-2)
• EPA Substance Registry System: Benzenamine, 4-methoxy-N-(1-phenylethylidene)-(2743-00-2)

Safety Data

• Hazardous Substances Data: 2743-00-2(Hazardous Substances Data)

Usage

General Description

Benzenamine, 4-methoxy-N-(1-phenylethylidene)- is a chemical compound with the molecular formula C16H17NO. It is a derivative of aniline and is commonly referred to as para-methoxy-N-(1-phenylethylidene)aniline. Benzenamine, 4-methoxy-N-(1-phenylethylidene)- is a yellow crystalline solid that is insoluble in water but soluble in organic solvents. It is used in the production of dyes and pigments, as well as in the synthesis of pharmaceuticals and other organic compounds. Its chemical structure and properties make it suitable for a variety of applications in the chemical and pharmaceutical industries.

Upstream product

• 104-94-9 4-methoxy-aniline 
• 98-86-2 acetophenone 
• 536-74-3 phenylacetylene 
• 126522-56-3 4-methoxy-N-(1-phenylethyl)aniline 
• 100-42-5 styrene 
• 20102-12-9 2-hydroxy-2-phenylpropionitrile 
• 98-81-7 1-bromovinylbenzene 
• 766-82-5 1-ethynyl-3-methyl-benzene 
• 100-17-4 para-methoxynitrobenzene 
• 4316-35-2 acetophenone dimethyl acetal 
• 13165-69-0 p-methoxy-N-sulfinylaniline 
• 26456-05-3 10-methylacridinium perchlorate 
• 36714-99-5 N-(1-(4-bromophenyl)ethylidene)-4-methoxybenzenamine 
• 100-58-3 phenylmagnesium bromide 

Downstream Products

• 76757-58-9 (4-Methoxy-phenyl)-[2,2,2-trichloro-1-phenyl-eth-(E)-ylidene]-amine 
• 99339-14-7 N-<2-(4-methoxyphenylimino)-2-phenylethylidene>phenylamine N-oxide 
• 84905-14-6 N-p-methoxyphenyl-N-α-styrylbenzoylpyruvamide 
• 855-31-2 1-(4-methoxyphenyl)-2,5-diphenyl-1H-pyrrole 
• 126522-56-3 4-methoxy-N-(1-phenylethyl)aniline 
• 2743-01-3 (R)-N-(4-methoxyphenyl)-(1-phenylethyl)amine 
• 156092-13-6 (S)-4-methoxy-N-(1-phenylethyl)aniline 
• 860773-41-7 4-(2'-acetylphenyl)benzoic acid ethyl ester 
• 2627-86-3 (S)-1-phenyl-ethylamine 
• 10295-35-9 2,2-dichloro-1-(4-methoxyphenyl)-3-phenylaziridine 

Relevant articles and documents

Gold(I) complexes bearing ring-fused benzoxazine-derived triazolylidenes and their use in C–N bond-forming processes

We report the synthesis and full characterization of a novel series of ring-fused benzoxazine-derived triazolium salts (1a–c) and their corresponding triazolylidene gold(I) complexes (2a–c). All new compounds were fully characterized by means of 1H and 13C NMR spectroscopy, elemental analyses, and mass spectroscopy and in the case of triazoliums 1a and 1b by single-crystal X-ray diffraction. The new triazolylidene gold complexes (2a–c) were tested as precatalysts in the hydroamination and hydrohydrazination of terminal alkynes employing aniline derivatives and hydrazine as nitrogen sources, respectively.

Synthesis and Catalytic Applications of Multinuclear Gold(I)-1,2,3-Triazolylidene Complexes

A series of mono- to trinuclear gold(I) complexes (1–3) supported by oxo-functionalized 1,2,3-triazolylidenes have been prepared. All new compounds were fully characterized by means of 1H and 13C NMR spectroscopy, elemental analyses, and in the case of complexes 1 and 2 by x-ray diffraction. The catalytic performance of the new triazolylidene gold complexes was tested in several hydroelementation and cyclization processes employing a variety of alkynes as starting materials. According to the overall results, the trinuclear complex 3 displayed the highest catalytic activity in all processes, providing good to excellent yields under mild reaction conditions.

Towards the rational design of ylide-substituted phosphines for gold(i)-catalysis: From inactive to ppm-level catalysis

The implementation of gold catalysis into large-scale processes suffers from the fact that most reactions still require high catalyst loadings to achieve efficient catalysis thus making upscaling impractical. Here, we report systematic studies on the impa