32291-88-6

Basic information

• Product Name: (E)-(4-nitrostyryl)(p-tolyl)sulfane
• Synonyms: (E)-(4-nitrostyryl)(p-tolyl)sulfane
• CAS NO: 32291-88-6
• Molecular Weight: 271.34
• Mol File: 32291-88-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-(4-nitrostyryl)(p-tolyl)sulfane(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(4-nitrostyryl)(p-tolyl)sulfane(32291-88-6)
• EPA Substance Registry System: (E)-(4-nitrostyryl)(p-tolyl)sulfane(32291-88-6)

Safety Data

• Hazardous Substances Data: 32291-88-6(Hazardous Substances Data)

Upstream product

• 106-45-6 para-thiocresol 
• 100-13-0 4-nitrostyrene 
• 10154-77-5 3-[(4-methylphenyl)sulfonyl]propanoic acid methyl ester 
• 937-31-5 (4-Nitrophenyl)acetylene 

Relevant articles and documents

Transition Metal-Free C-H Thiolation via Sulfonium Salts Using β-Sulfinylesters as the Sulfur Source

We disclose a direct C(sp)-, C(sp2)-, and C(sp3)-H thiolation reaction using β-sulfinylesters as the versatile sulfur source. The key step of this protocol is chemoselective C-S bond cleavage of the sulfonium salts that are formed in situ from the corresponding alkenes, alkynes, and 1,3-dicarboxyl compounds with β-sulfinylesters. The successful capture of the acrylate byproduct supports a retro-Michael reaction mechanism.