33931-80-5Relevant articles and documents
DIRECT SYNTHESIS OF ETHYLIDENE DIACETATE FROM METHYL ACETATE AND SYNTHESIS GAS BY MIXED RHODIUM-PALLADIUM CATALYST
Kudo, Kiyoshi,Mori, Sadayuki,Sugita, Nobuyuki
, p. 265 - 268 (1985)
The direct hydrocarbonylation of methyl acetate to ethylidene diacetate by use of rhodium-palladium mixed catalysts with iodide and basic promoters in acetic acid solution was investigated at 160 deg under 200 kg/cm2 of synthesis gas(H2/CO=1/1).Conversion of methyl acetate up to 93percent and yield to ethylidene diacetate as high as 68percent were obtained.