349453-01-6

Basic information

• Product Name: 1,2-bis(5-tert-butyl-2-methoxymethylbenzyl)benzene
• Synonyms: 1,2-bis(5-tert-butyl-2-methoxymethylbenzyl)benzene
• CAS NO: 349453-01-6
• Molecular Weight: 458.684
• Mol File: 349453-01-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2-bis(5-tert-butyl-2-methoxymethylbenzyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-bis(5-tert-butyl-2-methoxymethylbenzyl)benzene(349453-01-6)
• EPA Substance Registry System: 1,2-bis(5-tert-butyl-2-methoxymethylbenzyl)benzene(349453-01-6)

Safety Data

• Hazardous Substances Data: 349453-01-6(Hazardous Substances Data)

Upstream product

• 246139-76-4 2-bromo-1-(bromomethyl)-4-(tert-butyl)benzene 
• 61024-94-0 2-bromo-4-tert-butyl-1-methylbenzene 

Downstream Products

• 349453-02-7 1,2-bis(2-bromomethyl-5-tert-butylbenzyl)benzene 

Relevant articles and documents

Medium-sized cyclophanes. Part 55. Synthesis and conformational studies of [2.1.1] orthocyclophanes

[2.1.1]Orthocyclophanes 2 are prepared by pyrolysis of the corresponding 2-thia[3.1.1]orthocyclophane 2,2-dioxides 9, which are prepared by the reaction of 1,2-bis(2-bromomethylbenzyl)benzenes 7 with Na2S in ethanol under high dilution conditions, followed by oxidation with m-chloroperbenzoic acid. The conformational studies on [2.1.1]orthocyclophanes 2, which adopt flexible saddle and crown structures in comparison with the corresponding 10,15-dihydro-5H-tribenzo[a,d,g]cyclononene ([1.1.1]orthocyclophane) 1, are discussed.