38418-10-9

Basic information

• Product Name: p-methylbenzyl benzoate
• Synonyms: p-methylbenzyl benzoate;4-Methylbenzenemethanol benzoate
• CAS NO: 38418-10-9
• Molecular Formula: C₁₅H₁₄O₂
• Molecular Weight: 226.27046
• EINECS: 253-921-7
• Mol File: 38418-10-9.mol
• Article Data: 33

Chemical Properties

• Boiling Point: 341.4°C at 760 mmHg
• Flash Point: 152.5°C
• Appearance: /
• Density: 1.107g/cm³
• Vapor Pressure: 8.05E-05mmHg at 25°C
• Refractive Index: 1.573
• CAS DataBase Reference: p-methylbenzyl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: p-methylbenzyl benzoate(38418-10-9)
• EPA Substance Registry System: p-methylbenzyl benzoate(38418-10-9)

Safety Data

• Hazardous Substances Data: 38418-10-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H14O2/c1-12-7-9-13(10-8-12)11-17-15(16)14-5-3-2-4-6-14/h2-10H,11H2,1H3

Upstream product

• 139259-94-2 N-(acetyloxy)-N-(((4-methylphenyl)methyl)oxy)benzamide 
• 589-18-4 4-Methylbenzyl alcohol 
• 98-88-4 benzoyl chloride 
• 65-85-0 benzoic acid 
• 98-86-2 acetophenone 
• 2902-69-4 2,2,2-trichloroacetophenone 
• 93-97-0 benzoic acid anhydride 
• 93-58-3 benzoic acid methyl ester 
• 93-99-2 benzoic acid phenyl ester 
• 55-21-0 benzamide 
• 104-81-4 4-Methylbenzyl bromide 
• 611-74-5 N,N-dimethylbenzamide 
• 614-16-4 Benzoylacetonitrile 
• 4231-62-3 1-benzoyl-1H-benzotriazole 

Downstream Products

• 120-51-4 benzoic acid benzyl ester 
• 5467-99-2 4-methylbenzoic acid benzyl ester 
• 21086-87-3 4-methylbenzyl 4-methylbenzoate 
• 100-51-6 benzyl alcohol 

Relevant articles and documents

N-Aroylbenzotriazoles as Efficient Reagents for o-Aroylation in Absence of Organic Solvent

N-Aroylbenzotriazoles have been shown to be efficient reagents for esterification in the absence of organic solvent. Grinding of N-aroylbenzoytiazoles with twofold excess of alcohols for a couple of hours at room temperature gave corresponding esters in high percentage of yields.

Catalytic conversion of ketones to esters: Via C(O)-C bond cleavage under transition-metal free conditions

The catalytic conversion of ketones to esters via C(O)-C bond cleavage under transition-metal free conditions is reported. This catalytic process proceeds under solvent-free conditions and offers an easy operational procedure, broad substrate scope with excellent selectivity, and reaction scalability. This journal is

Bu 4 NI-Catalyzed C-C Bond Cleavage and Oxidative Esteri??cation of Allyl Alcohols with Toluene Derivatives

A novel oxidative esterification of 1-arylprop-2-en-1-ols with toluene derivatives catalyzed by tetrabutylammonium iodide (TBAI) is reported. The optimization of the reaction conditions illustrates that each of experiment parameters including the catalyst, solvent, and oxidant is significant for present oxidative functionalization. This metal-free protocol has a broad substrate scope including the halogen groups for further functionalization and enriches the reactivity profile of allyl alcohol and toluene derivatives. In addition, this protocol represents a new transformation of allyl alcohol involving C-C bond cleavage and C-O bond forming.