390427-07-3

Basic information

• Product Name: 2-(tert-Butoxycarbonylaminomethyl)phenol
• Synonyms: [(2-Hydroxyphenyl)methyl]-carbamic Acid 1,1-Dimethylethyl Ester;2-(tert-Butoxycarbonylaminomethyl)phenol;2-(Boc-aMinoMethyl)phenol;tert-butyl 2-hydroxybenzylcarbamate
• CAS NO: 390427-07-3
• Molecular Formula: C₁₂H₁₇NO₃
• Molecular Weight: 223.27
• Product Categories: All Aliphatics;Aliphatics;Aromatics;Aliphatics, Aromatics
• Mol File: 390427-07-3.mol
• Article Data: 9

Chemical Properties

• Melting Point: 85-87°C
• Boiling Point: 369.4±25.0 °C(Predicted)
• Appearance: /
• Density: 1.121±0.06 g/cm3(Predicted)
• Storage Temp.: Refrigerator
• Solubility: Acetone, Chloroform, Dichloromethane, Ethyl Acetate, Methanol
• PKA: 9.79±0.30(Predicted)
• CAS DataBase Reference: 2-(tert-Butoxycarbonylaminomethyl)phenol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(tert-Butoxycarbonylaminomethyl)phenol(390427-07-3)
• EPA Substance Registry System: 2-(tert-Butoxycarbonylaminomethyl)phenol(390427-07-3)

Safety Data

• Hazardous Substances Data: 390427-07-3(Hazardous Substances Data)

Usage

Chemical Properties

White Solid

Upstream product

• 90-02-8 salicylaldehyde 
• 4248-19-5 tert-butyl carbazate 
• 24424-99-5 di-tert-butyl dicarbonate 
• 89-95-2 2-methyl-benzyl alcohol 
• 94-67-7 salicylaldehyde-oxime 
• 932-30-9 2-Hydroxybenzylamine 

Downstream Products

• 932-30-9 2-Hydroxybenzylamine 
• 1206675-01-5 (2-hydroxyphenyl)methanaminium acetate 
• 61626-91-3 o-hydroxyphenylmethylamine hydrochloride 

Relevant articles and documents

Colorimetric anion sensing by porphyrin-based anion receptors

Porphyrin derivatives 1-4 with H-bond donors and/or color-reporting chromophoric unit were synthesized and studied as anion-binding receptors. 1 and 2 exhibited binding selectivity in the order of AcO->H2PO4-?Cl-, Br-, I- in DMSO-d6. Color change tests with several different anions for colorimetric anion sensors (3 and 4) resulted in selectivities for F-, AcO- and H2PO4- in organic solution. While 1 and 2 exhibited good selectivities for AcO- and H2PO4-, 3 and 4 showed a dramatic color change for F- due to increased interaction with a nitrophenylazo phenolic OH group.

Preparation method of salicylamine acetate

The invention discloses a preparation method of salicylamine acetate. The method comprises the following steps: (1) performing amino protection on salicylaldehyde with a structure shown in formula 1 to obtain a compound with a structure shown in formula 2

Emergent Self-Assembly Pathways to Multidimensional Hierarchical Assemblies using a Hetero-Seeding Approach

The controlled formation of complex and functional 1-, 2-, and 3D hierarchical assemblies from molecular building blocks represents a key current challenge. Herein, we report the use of a seeded growth approach for a series of perylenediimide-based molecules (PDIs 1–4) to access otherwise inaccessible self-assembly pathways that yield complex hierarchical structures. The key to the new approach is to use hetero-seeds which possess a different composition and morphology from that of the molecular building block. For example, a nanotube seed (from PDI 3) and a microribbon seed (from PDI 4) were found to initiate different self-assembly pathways for PDI 1, which normally assembles to yield nanocoils. This led to the formation of unprecedented 3D scroll-like and scarf-like hierarchical nanostructures, respectively. Also, the hetero-seeds from PDI 3 initiate hidden self-assembly pathways of PDI 2 to generate 1D tubular heterojunctions. Significantly, this new strategy offers new opportunities to create emergent and functional hierarchical and complex structures from small molecule precursors.