41422-93-9

Basic information

• Product Name: Silane, chlorodiphenyl-2-propenyl-
• CAS NO: 41422-93-9
• Molecular Formula: C15H15ClSi
• Molecular Weight: 258.823
• Mol File: 41422-93-9.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Silane, chlorodiphenyl-2-propenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, chlorodiphenyl-2-propenyl-(41422-93-9)
• EPA Substance Registry System: Silane, chlorodiphenyl-2-propenyl-(41422-93-9)

Safety Data

• Hazardous Substances Data: 41422-93-9(Hazardous Substances Data)

Upstream product

• 80-10-4 diphenylsilyl dichloride 
• 346713-20-0 allylsamarium bromide 
• 1829-58-9 (prop-2-enyl)diphenylsilane 
• 107-37-9 allyltrichlorosilane 
• 106-95-6 allyl bromide 
• 10519-88-7 diallyldiphenylsilane 

Downstream Products

• 1027257-29-9 (+/-)-2-(allyldiphenylsilanyloxy)-3-methylbutyronitrile 
• 1052679-81-8 (2R)-2-allyldiphenylsilanyloxy-2-[5,6-dimethoxy-5,6-dimethyl-1,4-dioxan-2-yl]acetonitrile 
• 1268266-66-5 1-(allyldiphenylsilyl)-2-(1-hexynyl)benzene 
• 1268267-31-7 [2-(1-allyl-(E)-1-hexenyl)phenyl]dimethylsilyl methyl ether 
• 1268267-30-6 9-hexylidene-7-methoxy-5,5-diphenyl-6,7,8,9-tetrahydro-5-sila-benzocycloheptene 
• 1268267-11-3 {2-[(E)-1-(2-methoxybenzylidene)-3-butenyl]phenyl}diphenylsilanol 
• 1268267-09-9 {2-[(E)-1-(2-bromobenzylidene)-3-butenyl]phenyl}diphenylsilanol 
• 1268267-07-7 {2-[(E)-1-(4-bromobenzylidene)-3-butenyl]phenyl}diphenylsilanol 
• 1268267-05-5 {2-[(E)-1-(4-methoxycarbonylbenzylidene)-3-butenyl]phenyl}diphenylsilanol 
• 1268267-03-3 {2-[(E)-1-benzylidene-3-butenyl]phenyl}diphenylsilanol 
• 1268266-97-2 [2-(1-allyl-(E)-1,4-pentadienyl)phenyl]diphenylsilanol 
• 1268266-95-0 [2-(E)-1-(ethylidene-3-butenyl)phenyl]diphenylsilanol 
• 1268266-93-8 [2-(1-methylene-3-butenyl)phenyl]diphenylsilanol 
• 1268267-15-7 [2-(1-allyl-(E)-2-deuterio-1-hexenyl)phenyl]diphenylsilanol 

Relevant articles and documents

Selective mono- and di-allylation and allenylation of chlorosilanes using indium

Allyl and allenyl groups have been introduced into silicon systems by the allylation and allenylation of chlorosilanes using allyl bromide or propargyl bromide with indium. The allylation of chlorosilanes afforded a variety of aryl, aralkyl, and alkenyl substituted allylsilanes. By applying this method, the reactions of 1-bromo-3-methylbut-2-ene, 3-bromo-2-methylprop-1-ene and 3-bromobut-1-ene with chlorosilanes also proceed smoothly to give regioselectively allylic rearrangement products in good yields. Mediated by indium, dichlorosilanes (R2SiCl2) and trichlorosilanes (RSiCl3) can either afford monoallylated silanes or diallylated silanes depending on the amount of allyl bromide and indium used.

Allylsilyl propargyl ethers as substrates for intramolecular Pauson-Khand reactions

Silyl ethers that are synthesized by coupling a propargylic alcohol with an allylsilyl chloride are shown to undergo sulfide-promoted Pauson-Khand reactions, affording bicyclic enones. Copyright Taylor & Francis Group, LLC.

Controlled introduction of allylic group to chlorosilanes

Allylation of chlorosilanes has been achieved with allylsamarium bromide, especially in a controlled manner. Thus allylation of trisubstituted chlorosilanes (R3SiCl) afforded a variety of aryl, aralkyl, and alkenyl substituted allylsilanes. Dichlorosilanes (R2SiCl2) can either afford monoallylated silanes or diallylated silanes depending on the amount of allylsamarium bromide used. Similarly, trichlorosilanes (RSiCl3) can selectively afford mono-, di-, and tri-allylation products. Finally, perchlorosilane (SiCl4) was allylated stepwise and the corresponding silanes containing one, two, three or four allylic groups, respectively, were obtained in satisfactory yields.