4189-82-6

Basic information

• Product Name: Sulfonium, (4-methylphenyl)diphenyl-, bromide
• CAS NO: 4189-82-6
• Molecular Formula: C19H17S.Br
• Molecular Weight: 357.314
• Mol File: 4189-82-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Sulfonium, (4-methylphenyl)diphenyl-, bromide(CAS DataBase Reference)
• NIST Chemistry Reference: Sulfonium, (4-methylphenyl)diphenyl-, bromide(4189-82-6)
• EPA Substance Registry System: Sulfonium, (4-methylphenyl)diphenyl-, bromide(4189-82-6)

Safety Data

• Hazardous Substances Data: 4189-82-6(Hazardous Substances Data)

Upstream product

• 24702-37-2 S-(p-tolyl)-S-phenyl-N-(p-tolylsulfonyl)sulfilimine 
• 106-38-7 para-bromotoluene 
• 945-51-7 1,1'-sulfinylbisbenzene 
• 3699-01-2 4-tolyl phenyl sulfide 
• 4294-57-9 para-methylphenylmagnesium bromide 

Downstream Products

• 1135815-31-4 C₁₅H₁₉F₂O₇S^(1-)*C₁₉H₁₇S⁽¹⁺⁾ 
• 1153716-27-8 C₉H₉F₂O₈S₂^(1-)*C₁₉H₁₇S⁽¹⁺⁾ 
• 1112983-16-0 C₉H₇F₂O₈S^(1-)*C₁₉H₁₇S⁽¹⁺⁾ 

Relevant articles and documents

PROCESS FOR PRODUCING TRIARYLSULFONIUM SALT

An object of the present invention is to provide a method for effectively producing a triarylsulfonium salt having a structure that only one aromatic ring of three aromatic rings on the cation portion thereof is different from the other two aromatic rings (hereinafter, abbreviated as a triarylsulfonium salt relating to the present invention) in a high yield without forming any byproduct. The present invention relates to a method for producing a triarylsulfonium salt represented by the general formula [4]: wherein, two R1's represent each hydrogen atom, halogen atom, alkyl group, haloalkyl group having 1 to 4 carbon atoms, alkoxy group, acyl group, hydroxyl group, amino group, nitro group or cyano group; R represents an aryl group which may have a substituent selected from a halogen atom, an alkyl group, a haloalkyl group having 1 to 4 carbon atoms, an alkoxy group, an alkylthio group, a N-alkylcarbamoyl group and a carbamoyl group, and the above substituent is different from one represented by the above R1; and A1 represents a strong acid residue, comprising reacting a diaryl sulfoxide represented by the general formula [1]: wherein, R1 represents the same as above, and an aryl Grignard reagent represented by the general formula [2]: ????????RMgX?????[2] wherein, X represents a halogen atom; R represents the same as above, in the presence of an activator with high affinity for oxygen of 3 to 7.5 equivalents relative to the above diaryl sulfoxide, and then reacting the resultant reaction mixture with a strong acid represented by the general formula [3]: ????????HA1?????[3] wherein, A1 represents the same as above, or a salt thereof.