4359-31-3

Basic information

• Product Name: 4,5-Dimethyl-2-phenyl-1,3-dioxolane
• Synonyms: 4,5-Dimethyl-2-phenyl-1,3-dioxolane
• CAS NO: 4359-31-3
• Molecular Formula: C₁₁H₁₄O₂
• Molecular Weight: 178.2277
• Mol File: 4359-31-3.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 251.8°Cat760mmHg
• Flash Point: 108.6°C
• Appearance: /
• Density: 1.018g/cm³
• Vapor Pressure: 0.0319mmHg at 25°C
• Refractive Index: 1.493
• CAS DataBase Reference: 4,5-Dimethyl-2-phenyl-1,3-dioxolane(CAS DataBase Reference)
• NIST Chemistry Reference: 4,5-Dimethyl-2-phenyl-1,3-dioxolane(4359-31-3)
• EPA Substance Registry System: 4,5-Dimethyl-2-phenyl-1,3-dioxolane(4359-31-3)

Safety Data

• Hazardous Substances Data: 4359-31-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C11H14O2/c1-8-9(2)13-11(12-8)10-6-4-3-5-7-10/h3-9,11H,1-2H3

Upstream product

• 6982-25-8 d,l-2,3-butanediol 
• 774-48-1 (diethoxymethyl)benzene 
• 100-52-7 benzaldehyde 
• 513-85-9 2.3-butanediol 

Downstream Products

• 79449-86-8 4-Phenyl-1,2-dimethyl-3-oxa-1-butanol-4-d 
• 620-05-3 iodomethylbenzene 
• 38739-85-4 (2RS,3RS)-butane-2,3-diol monobenzoate 
• 59517-16-7 2-hydroxy-1-methylpropyl benzoate 

Relevant articles and documents

2,4,4,6-Tetrabromo-2,5-cyclohexadienone (TABCO) as a versatile, efficient, and chemoselective catalyst for the acetalization and transacetalization of carbonyl compounds, the preparation of acetonides from epoxides and acylals (1,1-diacetates) from aldehydes

The efficient and chemoselective preparation of acetals and ketals from carbonyl compounds, transacetalization reactions, the conversion of epoxides to acetonides, and the preparation of acylals from aldehydes in the presence of catalytic amounts of 2,4,4,6-tetrabromo-2,5-cyclohexadienone (TABCO) are described.

Synthese d'acetals cycliques dans des conditions douces; Applications a l'acetalisation du chloramphenicol

Acetalization of 1-2 and 1-3 diols, even as sterically crowded as chloramphenicol, by carbonyl derivatives with substituents of various sizes has been performed at room temperature under mild conditions, by using heterogeneous catalysis (sulfonated polystyrene) in the presence of molecular sieves.Several new acetals of chloramphenicol have thus been obtained in good yields, isolated and characterized.