4464-76-0

Basic information

• Product Name: dihydroanisoin
• Synonyms: dihydroanisoin
• CAS NO: 4464-76-0
• Molecular Formula: C₁₆H₁₈O₄
• Molecular Weight: 0
• Mol File: 4464-76-0.mol
• Article Data: 133

Chemical Properties

• Boiling Point: 456.8°C at 760 mmHg
• Flash Point: 230.1°C
• Appearance: /
• Density: 1.205g/cm³
• Vapor Pressure: 3.88E-09mmHg at 25°C
• Refractive Index: 1.589
• CAS DataBase Reference: dihydroanisoin(CAS DataBase Reference)
• NIST Chemistry Reference: dihydroanisoin(4464-76-0)
• EPA Substance Registry System: dihydroanisoin(4464-76-0)

Safety Data

• Hazardous Substances Data: 4464-76-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C16H18O4/c1-19-13-7-3-11(4-8-13)15(17)16(18)12-5-9-14(20-2)10-6-12/h3-10,15-18H,1-2H3

Upstream product

• 556-56-9 allyl iodid 
• 123-11-5 4-methoxy-benzaldehyde 
• 105-13-5 4-Methoxybenzyl alcohol 
• 119-52-8 4,4'-dimethoxybenzoin 
• 1226-42-2 1,2-bis(4-methoxyphenyl)-1,2-ethanedione 
• 100-09-4 4-methoxybenzoic acid 
• 4705-34-4 1,2-bis(4-methoxyphenyl)ethene 
• 4180-23-8 E-1-(4'-methoxyphenyl)prop-1-ene 
• 1185984-60-4 (S)-3-benzyloxy-1-pyrroline N-oxide 
• 100-52-7 benzaldehyde 
• 78-94-4 methyl vinyl ketone 
• 611-74-5 N,N-dimethylbenzamide 
• 588-72-7 [(E)-2-bromoethenyl]benzene 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 61732-72-7 meso-1,2-dibromo-1,2-di(4-methoxyphenyl)-2-ethane 
• 61732-76-1 1,2-dichloro-1,2-bis(4-methoxyphenyl)ethane 
• 123-11-5 4-methoxy-benzaldehyde 
• 100-09-4 4-methoxybenzoic acid 
• 120-44-5 1,4-di(4-methoxyphenyl)ethanone 
• 90-96-0 bis(p-methoxyphenyl)methanone 
• 5032-08-6 2,2-di-(4-methoxyphenyl)acetaldehyde 
• 4705-34-4 4,4'-dimethoxystilbene 
• 4705-34-4 1,2-bis(4-methoxyphenyl)ethene 
• 588-59-0 stilbene 
• 87-87-6 2,3,5,6-tetrachlorobenzene-1,4-diol 
• 1227004-90-1 1,2-N,N’-bis(4-methoxyphenylamino)-1,2-di(4-methoxyphenyl)ethane 
• 122798-27-0 (-)-(2S,3S)-1,2-bis(4-methoxyphenyl)ethane1,2-diol 
• 7248-16-0 2,3-bis(4-methoxyphenyl)quinoxaline 

Relevant articles and documents

Mo–Catalyzed One-Pot Synthesis of N-Polyheterocycles from Nitroarenes and Glycols with Recycling of the Waste Reduction Byproduct. Substituent-Tuned Photophysical Properties

A catalytic domino reduction–imine formation–intramolecular cyclization–oxidation for the general synthesis of a wide variety of biologically relevant N-polyheterocycles, such as quinoxaline- and quinoline-fused derivatives, and phenanthridines, is reported. A simple, easily available, and environmentally friendly dioxomolybdenum(VI) complex has proven to be a highly efficient and versatile catalyst for transforming a broad range of starting nitroarenes involving several redox processes. Not only is this a sustainable, step-economical as well as air- and moisture-tolerant method, but also it is worth highlighting that the waste byproduct generated in the first step of the sequence is recycled and incorporated in the final target molecule, improving the overall synthetic efficiency. Moreover, selected indoloquinoxalines have been photophysically characterized in cyclohexane and toluene with exceptional fluorescence quantum yields above 0.7 for the alkyl derivatives.

Oxidative carbon-carbon bond cleavage of 1,2-diols to carboxylic acids/ketones by an inorganic-ligand supported iron catalyst

The carbon-carbon bond cleavage of 1,2-diols is an important chemical transformation. Although traditional stoichiometric and catalytic oxidation methods have been widely used for this transformation, an efficient and valuable method should be further explored from the views of reusable catalysts, less waste, and convenient procedures. Herein an inorganic-ligand supported iron catalyst (NH4)3[FeMo6O18(OH)6]·7H2O was described as a heterogeneous molecular catalyst in acetic acid for this transformation in which hydrogen peroxide was used as the terminal oxidant. Under the optimized reaction conditions, carbon-carbon bond cleavage of 1,2-diols could be achieved in almost all cases and carboxylic acids or ketones could be afforded with a high conversion rate and high selectivity. Furthermore, the catalytic system was used efficiently to degrade renewable biomass oleic acid. Mechanistic insights based on the observation of the possible intermediates and control experiments are presented.

Oxidative and Redox-Neutral Approaches to Symmetrical Diamines and Diols by Single Electron Transfer/Hydrogen Atom Transfer Synergistic Catalysis

Homocoupling reactions of benzylamines and benzyl alcohols were examined under synergistic catalysis conditions with a photoredox catalyst and thiobenzoic acid as a hydrogen atom abstractor. When pivalaldehyde was used as an electron acceptor, oxidative dimerization proceeded selectively, whereas the use of benzaldehydes or iminium ions as electron acceptors resulted in redox-neutral coupling. These reactions afforded symmetrical 1,2-diamines and 1,2-diols in good yields.