4569-35-1Relevant articles and documents
Regio- and stereospecific cleavage of silyl- and disilylepoxides with lithium diphenylphosphide
Cuadrado, Purificacion,Gonzalez-Nogal, Ana M.,Sarmentero, M. Angeles
, p. 4491 - 4497 (2007/10/03)
Unsubstituted or α- and β-C-substituted silylepoxides react stereospecifically with lithium diphenylphosphide, optionally followed by methylation, to give vinylphosphonium iodides or vinylphosphine oxides resulting from α-opening and silyl enol ethers, vi
PREPARATION OF DIPHENYLVINYLPHOSPHINE OXIDES BY THE PCP PROCESS. CHOICE OF THE LEAVING CROUP.
Savignac, Philippe,Teulade, Marie-Paule,Aboujaoude, Elie Elia,Collignon, Noel
, p. 1559 - 1568 (2007/10/02)
Carbanionic conversion of alkyl into vinylphosphonates is extended to the preparation of diphenylvinylphosphine oxides.Obtention of pure products in optimized yields is closely related to the choice of the phosphate leaving group.