4614-22-6

Basic information

• Product Name: 3-benzylbenzothiazolium
• Synonyms: 3-benzylbenzothiazolium
• CAS NO: 4614-22-6
• Molecular Formula: Br*C₁₄H₁₂NS
• Molecular Weight: 306.2208
• Mol File: 4614-22-6.mol
• Article Data: 7

Chemical Properties

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: 3-benzylbenzothiazolium(CAS DataBase Reference)
• NIST Chemistry Reference: 3-benzylbenzothiazolium(4614-22-6)
• EPA Substance Registry System: 3-benzylbenzothiazolium(4614-22-6)

Safety Data

• Hazardous Substances Data: 4614-22-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H12NS.BrH/c1-2-6-12(7-3-1)10-15-11-16-14-9-5-4-8-13(14)15;/h1-9,11H,10H2;1H/q+1;/p-1

Upstream product

• 95-16-9 1,3-Benzothiazole 
• 100-39-0 benzyl bromide 

Downstream Products

• 30015-70-4 4-benzyl-2-phenyl-2,3-dihydro-4H-benzothiazin-3-one 
• 30015-74-8 4-benzyl-2-p-tolyl-4H-benzo[1,4]thiazin-3-one 
• 30015-73-7 4-benzyl-2-(4-chloro-phenyl)-4H-benzo[1,4]thiazin-3-one 
• 37128-00-0 3,3'-dibenzyl-3H,3'H-[2,2']bi[benzothiazolylidene] 
• 51479-81-3 2,3-dibenzyl-2,3-dihydro-2,2'-bibenzo[d]thiazole 
• 22291-74-3 3-benzylbenzo[d]thiazol-2(3H)-one 
• 65948-22-3 3-benzylbenzo[d]thiazol-2(3H)-imine 
• 33682-61-0 3-benzylbenzo[d]thiazole-2(3H)-thione 
• 56553-71-0 2,2'-disulfanediylbis(N-benzylaniline) 
• 30015-72-6 2,4-dibenzyl-2H-benzo[b][1,4]thiazin-3(4H)-one 

Relevant articles and documents

Radical [1,3] Rearrangements of Breslow Intermediates

Breslow intermediates that bear radical-stabilizing N substituents, such as benzyl, cinnamyl, and diarylmethyl, undergo facile homolytic C-N bond scission under mild conditions to give products of formal [1,3] rearrangement rather than benzoin condensatio

An efficient procedure for the synthesis of phenacyl and benzyl azolium salts using fluorous alcohols

An efficient procedure for the synthesis of phenacyl and benzyl azolium salts in 2,2,2-trifluoroethanol and 1,1,1,3,3,3-hexafluoroisopropanol as fluorous alcohols have been developed. This synthetic methodology has some advantages with the respect to yield, atom efficiency, solvent and reagents used and wastes generated when compared to the currently in use methods. Using this procedure, a range of phenacyl and benzyl azolium salts can be synthesized with good to excellent yields. The pure salts are separated from the reaction mixture by simple filtration and washing with dry ether.

Ruthenium(II) N,S-heterocyclic carbene complexes and transfer hydrogenation of ketones

A series of ruthenium(II) N,S-heterocyclic carbene (NSHC) complexes Ru IIX(RCOO)(PPh3)2(3-R′BzTh) (BzTh = benzothiazol-2-ylidene; R = Me, R′/X = Bz/Br (4), Pri/I (6), Bui/I (8); R = Et, R′/X = Bz/Br (