49669-32-1

Basic information

• Product Name: 6,6'-di(1,3-dioxolan-2-yl)-2,2'-bipyridine
• Synonyms: 6,6'-di(1,3-dioxolan-2-yl)-2,2'-bipyridine
• CAS NO: 49669-32-1
• Molecular Weight: 300.314
• Mol File: 49669-32-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6,6'-di(1,3-dioxolan-2-yl)-2,2'-bipyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 6,6'-di(1,3-dioxolan-2-yl)-2,2'-bipyridine(49669-32-1)
• EPA Substance Registry System: 6,6'-di(1,3-dioxolan-2-yl)-2,2'-bipyridine(49669-32-1)

Safety Data

• Hazardous Substances Data: 49669-32-1(Hazardous Substances Data)

Upstream product

• 109-04-6 2-bromo-pyridine 
• 34199-87-6 6-bromo-2-(1,3-dioxolan-2-yl)pyridine 

Downstream Products

• 49669-26-3 2,2'-bipyridine-6,6'-dicarbaldehyde 

Relevant articles and documents

Csp2-Br bond activation of Br-pyridine by neophylpalladacycle: Formation of binuclear seven-membered palladacycle and bipyridine species

In this work, the synthesis and reactivity of seven-membered palladacycles are described, and a novel bi-pyridine synthesis in a catalytic pathway is reported. Neophyl-palladacycle(i) reacts with an excess of 2-Br-pyridine, giving the desired new binuclear seven-membered palladacycle (1) and unexpectedly, a bipyridine complex, [Pd(BiPy)Br2]. ESI-HRMS experiments show that fragmentation of the Pd-Br bond in 1 can take place producing unusual two coordinated Pd(ii) molecular ions, [Pd(NeoPyR)]+.