503071-00-9

Basic information

• Product Name: [(2R,5R)-4-oxo-2-[(1S)-triisopropylsilanyloxyethyl]-[1,3]oxazinan-5-yl]carbamic acid benzyl ester
• CAS NO: 503071-00-9
• Molecular Weight: 450.651
• Mol File: 503071-00-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(2R,5R)-4-oxo-2-[(1S)-triisopropylsilanyloxyethyl]-[1,3]oxazinan-5-yl]carbamic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: [(2R,5R)-4-oxo-2-[(1S)-triisopropylsilanyloxyethyl]-[1,3]oxazinan-5-yl]carbamic acid benzyl ester(503071-00-9)
• EPA Substance Registry System: [(2R,5R)-4-oxo-2-[(1S)-triisopropylsilanyloxyethyl]-[1,3]oxazinan-5-yl]carbamic acid benzyl ester(503071-00-9)

Safety Data

• Hazardous Substances Data: 503071-00-9(Hazardous Substances Data)

Upstream product

• 503070-99-3 (5R)-[(4S)-(2-oxo-4-phenyloxazolidin-3-yl)]-(2R)-(1S-triisopropylsilanyloxyethyl)-[1,3]oxazinan-4-one 
• 198147-93-2 (5S)-1-[(4S)-(2-oxo-4-phenyl-1,3-oxazolidin-3-yl)]-5-(triisopropylsilyloxy)-2-trimethylsilyloxy-3-azahexa-1,3-diene 
• 501-53-1 benzyl chloroformate 

Downstream Products

• 93204-36-5 (R)-methyl 2-(((benzyloxy)carbonyl)amino)-3-hydroxypropanoate 

Relevant articles and documents

Enantioselective synthesis of protected D-serine from tetrahydrooxazin-4-one via a hetero Diels-Alder reaction

Hetero Diels-Alder reaction between 2-aza-3-trimethylsilyloxy-1,3-diene and aldehydes gives rise to tetrahydrooxazin-4-ones, useful intermediates in the synthesis of α-amino-β-hydroxy acids. Herein we report the complete stereoselective synthesis of D-serine Cbz-methyl ester.