50902-98-2

Basic information

• Product Name: Benzene, (2,3,3-trimethyl-1-cyclopropen-1-yl)-
• CAS NO: 50902-98-2
• Molecular Formula: C12H14
• Molecular Weight: 158.243
• Mol File: 50902-98-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, (2,3,3-trimethyl-1-cyclopropen-1-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (2,3,3-trimethyl-1-cyclopropen-1-yl)-(50902-98-2)
• EPA Substance Registry System: Benzene, (2,3,3-trimethyl-1-cyclopropen-1-yl)-(50902-98-2)

Safety Data

• Hazardous Substances Data: 50902-98-2(Hazardous Substances Data)

Upstream product

• 98-87-3 benzylidene dichloride 
• 503-17-3 dimethylacetylene 
• 917-54-4 methyllithium 
• 82323-73-7 4-methyl-3-phenyl-2-diazo-3-pentene 
• 82323-72-6 2,3-dimethyl-1-phenyl-1-diazo-2-butene 
• 52776-41-7 2,3-dimethyl-1-phenyl-2-butene-1-one 
• 5324-64-1 2-(benzenesulfonyl)ethynylbenzene 
• 119145-34-5 3,3-dimethyl-4-phenyl-5-(phenylsulfonyl)-3H-pyrazole 
• 119145-33-4 3,3-dimethyl-5-(methylsulfonyl)-4-phenyl-3H-pyrazole 
• 24378-05-0 methyl phenylethynyl sulfone 
• 82323-79-3 2,3-dimethyl-1-phenyl-2-buten-1-one tosylhydrazone 
• 109900-77-8 3,3-dimethyl-2-phenyl-1-(phenylsulfonyl)cyclopropene 
• 119145-30-1 3,3-dimethyl-1-(methylsulfonyl)-2-phenylcyclopropene 

Downstream Products

• 65103-89-1 2-Methoxy-3-phenyl-4-methyl-3-penten 
• 65103-90-4 1-Methoxy-1-phenyl-2,3-dimethyl-2-buten 
• 52776-41-7 2,3-dimethyl-1-phenyl-2-butene-1-one 
• 77734-67-9 3-methoxy-2,3-dimethyl-1-phenyl-1-butene 
• 53546-26-2 4-methyl-3-phenyl-3-penten-2-one 

Relevant articles and documents

Photochemistry of Cyclopropene Derivatives. 34. Photocycloaddition Reactions of 2-Alkenyl-Substituted Cyclopropenes

The sensitized irradiation of 2-(4-pentenyl)-substituted cyclopropenes produces tricyclo1,3>octanes by means of novel intramolecular cycloaddition.In dramatic contrast to the photochemical results, thermolysis affords a product co

Thermolysis of Vinyldiazomethanes as a Method for the Generation of Vinylcarbenes and a Comparison with Cyclopropene Photochemistry

The pyrolysis of the vinyldiazomethanes 6 (X = H), 8, 9, and 10 gives mixtures of 3H-pyrazoles and cyclopropenes.The kinetics and product distribution for each case lead to a determination of the rate of vinylcarbene formation and, therefore, a direct determination of the relative carbene stabilities.The conclusion is that carbene 14 is more stable than 15.These results are then used as a basis for a discussion of the carbenes generated from the singlet photochemistry of unsymmetrical cyclopropenes, 11.