511552-35-5

Basic information

• Product Name: (3-methyl-2-butenyl) 4-nitrophenyl carbonate
• Synonyms: (3-methyl-2-butenyl) 4-nitrophenyl carbonate
• CAS NO: 511552-35-5
• Molecular Weight: 251.239
• Mol File: 511552-35-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3-methyl-2-butenyl) 4-nitrophenyl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: (3-methyl-2-butenyl) 4-nitrophenyl carbonate(511552-35-5)
• EPA Substance Registry System: (3-methyl-2-butenyl) 4-nitrophenyl carbonate(511552-35-5)

Safety Data

• Hazardous Substances Data: 511552-35-5(Hazardous Substances Data)

Upstream product

• 7693-46-1 4-Nitrophenyl chloroformate 
• 556-82-1 3-methyl-2-buten-1-ol 

Downstream Products

• 648910-19-4 N-[(3-methyl-2-butenyl)oxycarbonyl]-2-phenylethylamine 
• 755026-31-4 phenethyl-carbamic acid 2-iodo-3-methoxy-3-methyl-butyl ester 
• 648910-27-4 N^α-benzyloxycarbonyl-N^ε-(3-methyl-2-butenyl)oxycarbonyl-L-lysine methyl ester 
• 648910-23-0 1-(3-methyl-2-butenyl)-4-(benzyloxycarbonyl)piperidine 
• 648910-24-1 N-(3-methyl-2-butenyl)oxycarbonyl-L-proline benzyl ester 
• 648910-21-8 N-[(3-methyl-2-butenyl)oxycarbonyl]-2-(1-cyclohexenyl)ethylamine 

Relevant articles and documents

Prenyl carbamates: Preparation and deprotection

Prenyloxycarbonylimidazole (PreocIm) and prenyl p-nitrophenyl carbonate (PreocOC6H4p-NO2), two substitutes for the unstable prenyl chloroformate, allowed an efficient introduction of the prenyloxycarbonyl group to a variety of primary and secondary amines. Deprotection of prenyl carbamates was readily achieved by, first their conversion to 2-iodo-3-methoxy-3-methylbutyl carbamates with iodine in methanol followed by reductive β-elimination with zinc powder. These reaction conditions are compatible with the presence of a number of functional groups such as Boc and Cbz carbamates, sulfides, double bonds, indoles and aromatic ethers.