56888-48-3Relevant articles and documents
Radical-Based C?C Bond-Forming Processes Enabled by the Photoexcitation of 4-Alkyl-1,4-dihydropyridines
Buzzetti, Luca,Prieto, Alexis,Roy, Sudipta Raha,Melchiorre, Paolo
supporting information, p. 15039 - 15043 (2017/11/20)
We report herein that 4-alkyl-1,4-dihydropyridines (alkyl-DHPs) can directly reach an electronically excited state upon light absorption and trigger the generation of C(sp3)-centered radicals without the need for an external photocatalyst. Selective excitation with a violet-light-emitting diode turns alkyl-DHPs into strong reducing agents that can activate reagents through single-electron transfer manifolds while undergoing homolytic cleavage to generate radicals. We used this photochemical dual-reactivity profile to trigger radical-based carbon–carbon bond-forming processes, including nickel-catalyzed cross-coupling reactions.
Novel Photocoupling Reaction in Two-Component Crystals of Tetracyanobenzene with Benzyl Cyanide
Ito, Yoshikatsu,Endo, Sotaro,Ohba, Shigeru
, p. 5974 - 5975 (2007/10/03)
-
Nucleophile-Assisted Cleavage of Silane Cation Radicals
Dinnocenzo, J. P.,Farid, S.,Goodman, J. L.,Gould, I. R.,Todd, W. P.,Mattes, S. L.
, p. 8973 - 8975 (2007/10/02)
-