57680-77-0

Basic information

• Product Name: adamantylmagnesium bromide
• Synonyms: adamantylmagnesium bromide
• CAS NO: 57680-77-0
• Molecular Weight: 239.438
• Mol File: 57680-77-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: adamantylmagnesium bromide(CAS DataBase Reference)
• NIST Chemistry Reference: adamantylmagnesium bromide(57680-77-0)
• EPA Substance Registry System: adamantylmagnesium bromide(57680-77-0)

Safety Data

• Hazardous Substances Data: 57680-77-0(Hazardous Substances Data)

Upstream product

• 768-90-1 1-Adamantyl bromide 
• 60-29-7 diethyl ether 

Downstream Products

• 54509-46-5 4-Adamantan-1-yl-2,4,6-tri-tert-butyl-cyclohexa-2,5-dienone oxime 
• 102147-48-8 1-(benzylsulfonyl)adamantane 
• 1402047-58-8 N-(1,1-diphenylethyl)adamantane-1-carboxamide 
• 59974-37-7 1-(4-fluorophenyl)adamantane 
• 183967-43-3 1-(4-(trifluoromethyl)phenyl)adamantane 
• 57822-54-5 1-[(1,1'-biphenyl)-4-yl]adamantane 
• 1459-55-8 4-(1-adamantyl)toluene 
• 726-94-3 1-(4-methoxyphenyl)adamantane 
• 59974-40-2 1-(4-chlorophenyl)adamantane 
• 665-66-7 amantadine hydrochloride 
• 224311-55-1 2-biphenyl 
• 1660-04-4 1-acetyladamantane 
• 60509-83-3 (adamantan-1-yl)diphenylphosphine oxide 
• 126683-93-0 1-Phenylphosphinoyl-adamantane 

Relevant articles and documents

SYNTHESIS OF 1-ADAMANTYLMAGNESIUM BROMIDE

The reaction of 1-bromoadamantane and magnesium was studied preparatively and kinetically.Under the normal conditions for the production of Grignard reagents 1-adamantylmagnesium bromide is formed with a yield of up 64percent.Molecular oxygen increases the rate of this reaction.The reaction rate is determined by the diffusion of the bromide to the surface of the magnesium, by the desorption of the organomagnesium compound to the surface of the magnesium, and by the presence and density of the "black layer".