5855-62-9

Basic information

• Product Name: 6-Quinolinol, 2,4-diphenyl-
• CAS NO: 5855-62-9
• Molecular Formula: C21H15NO
• Molecular Weight: 297.356
• Mol File: 5855-62-9.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 6-Quinolinol, 2,4-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Quinolinol, 2,4-diphenyl-(5855-62-9)
• EPA Substance Registry System: 6-Quinolinol, 2,4-diphenyl-(5855-62-9)

Safety Data

• Hazardous Substances Data: 5855-62-9(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 588-53-4 N-benzylidene-p-hydroxyaniline 
• 107931-50-0 N-benzylidene-4-(trityloxy)aniline 
• 5855-65-2 2,4-diphenyl-6-methoxyquinoline 
• 123-30-8 4-amino-phenol 
• 100-52-7 benzaldehyde 
• 103-14-0 4-(benzylamino)phenol 
• 120-46-7 1,3-diphenylpropanedione 
• 108-95-2 phenol 

Relevant articles and documents

Synthesis of quinolines involving electrophilic amination of arenes with sodium azide in polyphosphoric acid

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Efficient synthesis of 2,4-disubstituted quinolines: Calix[n]arene- catalyzed Povarov-hydrogen-transfer reaction cascade

A cascade process involving the Povarov reaction and hydrogen transfer catalyzed with p-sulfonic acid calix[4]arene was disclosed and afforded the synthesis of 2,4-disubstituted quinolines in good yields under appropriate conditions in a single pot proces

Annulation Reactions with Iron(III) Chloride: Oxidation of Imines

Aromatic imines react with phenylacetylene or styrene in an acetonitrile solution of iron(III) chloride to give quinolines 3 or their tetrahydro derivatives 11 together with variable amounts of products 4 arising from the reduction of the imines.The initial step appears to be a one-electron oxidation to generate iron(II) and an imine radical cation.When the reactions are carried out in the presence of stoichiometric amounts of tetrachloro-p-benzoquinone (chloranil), only quinolines 3 are obtained.