59115-45-6

Basic information

• Product Name: Anisole, p-2-naphthyl- (6CI,7CI)
• Synonyms: Anisole, p-2-naphthyl- (6CI,7CI)
• CAS NO: 59115-45-6
• Molecular Formula: C₁₇H₁₄O
• Molecular Weight: 234.29246
• Mol File: 59115-45-6.mol
• Article Data: 151

Chemical Properties

• Melting Point: 135-137℃ (ethanol )
• Appearance: /
• CAS DataBase Reference: Anisole, p-2-naphthyl- (6CI,7CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Anisole, p-2-naphthyl- (6CI,7CI)(59115-45-6)
• EPA Substance Registry System: Anisole, p-2-naphthyl- (6CI,7CI)(59115-45-6)

Safety Data

• Hazardous Substances Data: 59115-45-6(Hazardous Substances Data)

Upstream product

• 104-92-7 1-bromo-4-methoxy-benzene 
• 1523-11-1 naphthalen-2-yl acetate 
• 7294-51-1 2,4,6-tris(4-methoxyphenyl)boroxine 
• 1503-86-2 2-naphthyl pivalate 
• 5720-07-0 4-methoxyphenylboronic acid 
• 3857-83-8 2-naphthyl triflate 
• 33397-21-6 tris(4-methoxyphenyl)bismuth 
• 21473-01-8 2-naphthalenylmagnesium bromide 
• 34000-29-8 [E]-3-(p-methoxyphenyl)-1-(2-hydroxyphenyl)prop-2-en-1-one 
• 2471-91-2 1,3-dihydrobenzo[c]thiophene-2,2-dioxide 
• 580-13-2 2-bromonaphthalene 
• 416857-85-7 10-hydroxy-10-methyl-2,2-diphenyl-2H-pyrano[6,5-b]fluorene 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 7385-85-5 naphthalen-2-yl tosylate 

Downstream Products

• 6336-82-9 2-(4′-hydroxyphenyl)naphthalene 
• 933066-95-6 6-naphthalen-2-yl-2,2-diphenyl-2H-chromene 
• 125715-99-3 dibromo-(4-methoxy-phenyl)-[2]naphthyl-λ⁴-tellane 

Relevant articles and documents

Nickel-Catalyzed Direct Cross-Coupling of Aryl Sulfonium Salt with Aryl Bromide

The direct cross-couplings of aryl sulfonium salts with aryl halides could be achieved by using nickel as a reaction catalyst. The reactions proceeded efficiently via C-S bond activation in the presence of magnesium turnings and lithium chloride in THF at ambient temperature to afford the corresponding biaryls in moderate to good yields, potentially serving as an attractive alternative to conventional cross-coupling reactions employing preprepared organometallic reagents.

Visible Light Induced Aerobic Coupling of Arylboronic Acids Promoted by Hydrazone

A visible-light-induced oxidative coupling of arylboronic acids has been developed for the synthesis of biaryls. The reaction that employs polydentate hydrazones as the bifunctional catalyst works smoothly under room temperature. It is compatible with a w

Cobalt?NHC Catalyzed C(sp2)?C(sp3) and C(sp2)?C(sp2) Kumada Cross-Coupling of Aryl Tosylates with Alkyl and Aryl Grignard Reagents

The first cobalt-catalyzed cross-coupling of aryl tosylates with alkyl and aryl Grignard reagents is reported. The catalytic system uses CoF3 and NHCs (NHC=N-heterocyclic carbene) as ancillary ligands. The reaction proceeds via highly selective C?O bond functionalization, leading to the corresponding products in up to 98 % yield. The employment of alkyl Grignard reagents allows to achieve a rare C(sp2)?C(sp3) cross-coupling of C?O electrophiles, circumventing isomerization and β-hydride elimination problems. The use of aryl Grignards leads to the formation of biaryls. The C?O cross-coupling sets the stage for a sequential cross-coupling by exploiting the orthogonal selectivity of the catalytic system.