64222-28-2Relevant articles and documents
Enantioselective intermolecular carbon-carbon bond formation of glyoxylate imines with allylstannanes catalyzed by tropos BIPHEP-gold(I) complexes with Au-Au interactions
Kojima, Masafumi,Mikami, Koichi
, p. 13950 - 13953 (2011)
Interactions act: The enantioselective allylation reaction of glyoxylate imines catalyzed by tropos DM-BIPHEP-gold(I) complexes with an Au-Au interaction was developed to give a higher enantioselectivity than the atropos DM-BINAP-gold complexes without an
Visible-Light-Mediated, Chemo- and Stereoselective Radical Process for the Synthesis of C-Glycoamino Acids
Ji, Peng,Zhang, Yueteng,Wei, Yongyi,Huang, He,Hu, Wenbo,Mariano, Patrick A.,Wang, Wei
supporting information, p. 3086 - 3092 (2019/05/01)
An approach for efficient synthesis of C-glycosyl amino acids is described. Different from typical photoredox-catalyzed reactions of imines, the new process follows a pathway in which α-imino esters serve as electrophiles in chemoselective addition reactions with nucleophilic glycosyl radicals. The process is highlighted by the mild nature of the reaction conditions, the highly stereoselectivity attending C-C bond formation, and its applicability to C-glycosylations using both armed and disarmed pentose and hexose derivatives.
Synthesis of new 1, 4-Dihydropyridines by addition-rearrangement process with imine derivatives and β-Ketoester as starting materials in solvent-free conditions
Xueming, Chen,Xiaoguang, Huang,Yunyun, Chen,Feng, He,Xingshu, Li
experimental part, p. 213 - 218 (2010/04/23)
N-substituted 1, 4-dihydropyridines bearing a carboxyl group at the 4-position were synthesized in solvent-free conditions with Cu2+ as the catalyst, imine and β-ketoester as starting materials. The possible mechanism which consists of addition
