64741-33-9

Basic information

• Product Name: 2,2'-Bipyridine, 6,6'-bis(diphenylphosphinyl)-
• CAS NO: 64741-33-9
• Molecular Formula: C34H26N2O2P2
• Molecular Weight: 556.54
• Mol File: 64741-33-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,2'-Bipyridine, 6,6'-bis(diphenylphosphinyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2'-Bipyridine, 6,6'-bis(diphenylphosphinyl)-(64741-33-9)
• EPA Substance Registry System: 2,2'-Bipyridine, 6,6'-bis(diphenylphosphinyl)-(64741-33-9)

Safety Data

• Hazardous Substances Data: 64741-33-9(Hazardous Substances Data)

Upstream product

• 64741-29-3 6,6'-bis-(diphenylphosphino)-2,2'-bipyridine 
• 49669-22-9 6,6'-Dibromo-2,2'-bipyridine 
• 65567-06-8 lithium diphenylphosphide 
• 4559-70-0 Diphenylphosphine oxide 
• 53344-72-2 6,6'-dichloro-2,2'-bipyridine 

Relevant articles and documents

An Approach to Nonsymmetric Bis(tertiary phosphine oxides) Comprising Heterocyclic Fragments via the Pd-Catalyzed Phosphorylation

Nonsymmetric tertiary phosphine oxides with different five- and six-membered heterocyclic fragments such as pyridine, 2,2′-bipyridine, 1,10-phenantroline, quinoline, imidazole, and thiazole were synthesized in good yields via the successive introduction of phosphine oxide groups into the initial dihalogenated heterocycles by means of Pd-catalyzed phosphorylation reaction. The synthesis of pyridine-type compounds is hindered by competing double coupling, while for five-membered heterocycles the principal difficulty is the dehalogenation. Both side processes were successfully suppressed by the use of an excess of a dihalide (which can be easily recovered during the product purification step), proper phosphine ligand for palladium, and nonpolar solvent such as toluene.

A NEW FAMILY OF AROMATIC POLYIMINE CHELATES SUBSTITUTED WITH TWO DIPHENYLPHOSPHINES

Reaction of lithium diphenylphosphide with vicinal nitrogen disubstituted polyimines such as 1,8-naphtyridine, 4'-phenyl-2,2',6',2''-terpyridine, 2,2'-bipyridine or 1,10-phenanthroline produces in high yield a new series of heterofunctional ligands.