65234-93-7Relevant articles and documents
Kinetic Study of the Pyridine-Catalyzed Selenolactonization of 4-Pentenoic Acid
Kosti?, Marina D.,Mihajlovi?, Kristina,Divac, Vera M.
, p. 2076 - 2081 (2020)
Abstract: The kinetics and mechanism of the pyridine-catalyzed cyclofunctionalization of 4-pentenoic acid by means of PhSeX (X = Cl, Br) have been investigated spectrophotometrically, under pseudo-first order reaction conditions. The influence of the reac
Preparation of selenofunctionalized heterocycles via iodosobenzene-mediated intramolecular selenocyclizations of olefins with diselenides
Wang, Peng-Fei,Yi, Wei,Ling, Yong,Ming, Liang,Liu, Gong-Qing,Zhao, Yu
supporting information, p. 2587 - 2591 (2021/03/15)
An intramolecular selenocyclizations of olefins mediated by a commercially available hypervalent iodine(III) reagent, PhIO, was developed. This method provided access to a wide range of selenenylated heterocycles under ambient conditions. The striking advantages of this protocol over all previous methods include mild reaction conditions, easy operation, good yields, high levels of functional group compatibility, large–scale application and suitability for the late-stage functionalization of complex molecules of biological importance.
Electrochemical Difunctionalization of Olefines: Access to Selenomethyl-Substituted Cyclic Ethers or Lactones
Meng, Xiu-Jin,Zhong, Ping-Fu,Wang, Yu-Mei,Wang, Heng-Shan,Tang, Hai-Tao,Pan, Ying-Ming
supporting information, p. 506 - 511 (2019/12/24)
A metal- and oxidant-free electrochemical method for preparing selenomethyl-substituted cyclic ethers or lactones via difunctionalization of olefines is presented. A series of selenomethyl-substituted cyclic ethers, particularly 9- and 11- membered, selen