65854-93-5

Basic information

• Product Name: Benzamide, N-(4-formylphenyl)-
• CAS NO: 65854-93-5
• Molecular Formula: C14H11NO2
• Molecular Weight: 225.247
• Mol File: 65854-93-5.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzamide, N-(4-formylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, N-(4-formylphenyl)-(65854-93-5)
• EPA Substance Registry System: Benzamide, N-(4-formylphenyl)-(65854-93-5)

Safety Data

• Hazardous Substances Data: 65854-93-5(Hazardous Substances Data)

Upstream product

• 556-18-3 4-aminobenzaldehyde 
• 98-88-4 benzoyl chloride 
• 19073-14-4 4-(1,3-dioxolan-2-yl)aniline 
• 87199-17-5 4-formylphenylboronic acid, 
• 19226-36-9 3-phenyl-5H-1,4,2-dioxazol-5-one 
• 619-66-9 4-Carboxybenzaldehyde 
• 65-85-0 benzoic acid 
• 623-04-1 4-aminobenzenemethanol 
• 179057-17-1 N-[4-(hydroxymethyl)phenyl] benzamide 
• 100-47-0 benzonitrile 
• 873-75-6 4-bromobenzenemethanol 
• 555-16-8 4-nitrobenzaldehdye 
• 2403-53-4 2-(4-nitrophenyl)-1,3-dioxolane 
• 619-45-4 4-methoxycarbonyl aniline 

Downstream Products

• 109515-87-9 benzoic acid-(4-selenosemicarbazonomethyl-anilide) 
• 205809-12-7 benzoic acid-[4-(3-oxo-3-phenyl-propenyl)-anilide] 
• 1143504-67-9 C₂₈H₂₄N₂O₄ 
• 492-70-6 1,2-diphenyl-1,2-ethanediol 
• 956-05-8 3-(4-aminophenyl)-1-phenyl-2-propen-1-one 

Relevant articles and documents

Visible-Light-Promoted Iron-Catalyzed N-Arylation of Dioxazolones with Arylboronic Acids

A visible-light-promoted and simple iron salt-catalyzed N-arylation was achieved efficiently under external photosensitizer-free conditions. Arylboronic acids and bench-stable dioxazolones were used for this cross-coupling reaction. This reaction features high reactivity, wide substrate scope, good functional group tolerance, simple operation procedure, and mild reaction conditions. Preliminary mechanistic investigations were conducted to support a radical pathway. This method may contribute to shift the paradigm of iron-catalyzed C-N bond construction and nitrene transfer chemistry.

Rhodium-catalyzed electrophilic amination of arylboronic acids with secondary hydroxylamines

A rhodium(III)-catalyzed electrophilic amination of arylboronic acids with secondary hydroxylamines has been developed. The rhodium catalysis is compatible with heteroarylboronic acids as well as acyl and alkoxycarbonyl protecting groups on the nitrogen of O-acylhydroxylamines, and the corresponding secondary anilines are obtained in good to excellent yields.

Palladium-Catalyzed Synthesis of Aryl Amides through Silanoate-Mediated Hydrolysis of Nitriles

A procedure for the formation of aryl amides through the palladium-catalyzed coupling of nitriles and aryl bromides, via the formation of intermediary silanoate derived imidate species is reported. Optimization was undertaken and examples of the process are described that furnish the products in up to 86% isolated yield.