67472-23-5

Basic information

• Product Name: Benzenemethanol, 2-hydroxy-a-2-propenyl-
• Synonyms: 1-(2-hydroxyphenyl)but-3-en-1-ol;2-(1-hydroxybut-3-enyl)phenol;1-(2-hydroxyphenyl)-3-buten-1-ol;2-(1-hydroxy-3-butenyl)phenol;1-(o-hydroxyphenyl)-3-buten-1-ol;2-(1'-hydroxybut-3'-enyl)phenol
• CAS NO: 67472-23-5
• Molecular Formula: C10H12O2
• Molecular Weight: 164.204
• Mol File: 67472-23-5.mol
• Article Data: 57

Chemical Properties

• Boiling Point: 269.0±10.0 °C(Predicted)
• Density: 1.116±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Benzenemethanol, 2-hydroxy-a-2-propenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 2-hydroxy-a-2-propenyl-(67472-23-5)
• EPA Substance Registry System: Benzenemethanol, 2-hydroxy-a-2-propenyl-(67472-23-5)

Safety Data

• Hazardous Substances Data: 67472-23-5(Hazardous Substances Data)

Upstream product

• 7393-43-3 tetraallyl tin 
• 90-02-8 salicylaldehyde 
• 1826-67-1 vinyl magnesium bromide 
• 163034-48-8 1-Allyl-1-(cyclohexyloxy)silacyclobutane 
• 108-95-2 phenol 
• 1730-25-2 allylmagnesium bromide 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 90-01-7 salicylic alcohol 
• 591-87-7 Allyl acetate 
• 24850-33-7 allyltributylstanane 
• 686769-17-5 2-(allyl-dimethyl-silanyl)-benzaldehyde 
• 35822-58-3 2-bromobenzaldehyde diethyl acetal 
• 100-52-7 benzaldehyde 
• 107-05-1 3-chloroprop-1-ene 

Relevant articles and documents

Visible Light-Promoted Recyclable Carbon Nitride-Catalyzed Dioxygenation of β,γ-Unsaturated Oximes

A visible-light-induced dioxygenation of β,γ-unsaturated oximes for the synthesis of diverse useful isoxazolines bearing a hydroxyl moiety was developed by employing graphitic carbon nitride (g-C3N4) as a heterogeneous photocatalyst under an air atmosphere. Noted that, the eminent advantages of this metal-free protocol include step economy, easy operation, a recyclable photocatalyst, external reductant-/oxidant-free and mild reaction conditions. Additionally, mechanistic studies indicated hydroxyl radical was generated under the photocatalysis of g-C3N4.

Synthesis of Flavanones via Palladium(II)-Catalyzed One-Pot β-Arylation of Chromanones with Arylboronic Acids

A total of 47 flavanones were expediently synthesized via one-pot β-arylation of chromanones, a class of simple ketones possessing chemically unactivated β sites, with arylboronic acids via tandem palladium(II) catalysis. This reaction provides a novel route to various flavanones, including natural products such as naringenin trimethyl ether, in yields up to 92percent.

Organocatalytic Asymmetric Domino Michael/Acyl Transfer Reaction Between α-Nitroketones and in situ-Generated ortho-Quinone Methides: Route to 2-(1-Arylethyl)phenols

An organocatalytic asymmetric domino Michael/acyl transfer reaction between α-nitroketones and o-quinone methides is disclosed. o-Quinone methides are generated in situ from 2-sulfonylmethylphenols in basic medium. With 10 mol% of bifunctional squaramide catalyst, high yields and excellent enantioselectivities are achieved for a variety of O-acyl 2-(1-arylethyl)phenols under mild reaction condition. (Figure presented.).