69456-96-8

Basic information

• Product Name: 2-phenylhydrazonopropanol
• CAS NO: 69456-96-8
• Molecular Weight: 164.207
• Mol File: 69456-96-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-phenylhydrazonopropanol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-phenylhydrazonopropanol(69456-96-8)
• EPA Substance Registry System: 2-phenylhydrazonopropanol(69456-96-8)

Safety Data

• Hazardous Substances Data: 69456-96-8(Hazardous Substances Data)

Upstream product

• 56-23-5 tetrachloromethane 
• 64-17-5 ethanol 
• 7732-18-5 water 
• 116-09-6 hydroxy-2-propanone 
• 100-63-0 phenylhydrazine 
• 64-19-7 acetic acid 
• 78-98-8 2-oxopropanal 

Downstream Products

• 7707-85-9 pyruvaldehyde bis-phenylhydrazone 

Relevant articles and documents

1,2,3-Triazoles produced from 5-Substituted N-Methoxytriazolium Salts

Five reactions, two of which are new, have been observed when 5-substituted 1-methoxy-2-phenyltriazolium salts react with nucleophiles: (i) addition to C-4 with elimination of methanol to give unsymmetrically 4,5-disubstituted triazoles; (ii) displacement of the 5-substituent followed by secondary reactions to give a symmetrically 4,5-disubstituted triazole, a 5-substituted triazole N-oxide, a 4-substituted triazole, or a disubstituted benzeneazoacetonitrile; (iii) deprotonation of the N-methoxy-group with elimination of formaldehyde; (iv) demethylation; (v) abstraction of an α-proton from a 5-alkyl group followed by nucleophilic addition and elimination of methanol to give an α-substituted 5-alkyltriazole.The reactions are of synthetic potential as a means of introducing one or two substituents in the 1,2,3-triazole system.