70767-39-4

Basic information

• Product Name: 6-bromo-1-chlorocyclohex-1-ene
• Synonyms: 6-bromo-1-chlorocyclohex-1-ene
• CAS NO: 70767-39-4
• Molecular Weight: 195.487
• Mol File: 70767-39-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-bromo-1-chlorocyclohex-1-ene(CAS DataBase Reference)
• NIST Chemistry Reference: 6-bromo-1-chlorocyclohex-1-ene(70767-39-4)
• EPA Substance Registry System: 6-bromo-1-chlorocyclohex-1-ene(70767-39-4)

Safety Data

• Hazardous Substances Data: 70767-39-4(Hazardous Substances Data)

Upstream product

• 56-23-5 tetrachloromethane 
• 2439-85-2 N-bromophthalimide 
• 930-66-5 1-chlorocyclohexene 
• 930-68-7 cyclohexenone 
• 3400-88-2 2-chlorocyclohex-2-en-1-one 
• 6498-39-1 2-chlorocyclohex-2-en-1-ol 

Downstream Products

• 120698-56-8 2-chloro-3-benzoylcyclohexene 

Relevant articles and documents

Synthesis of Halomethyl Isoxazoles/Cyclic Nitrones via Cascade Sequence: 1,2-Halogen Radical Shift as a Key Link

A novel iminoxyl radical-promoted dichotomous regioselective 5-exo-trig cyclization onto vinylic halogen/1,2-halogen radical shift sequence is developed for the synthesis of halomethyl isoxazoles/cyclic nitrones using β-halo-β,?- and ?-halo-?,?-unsaturated ketoximes as the substrates and PhI(OAc)2/TEMPO as the oxidation system. DFT calculations reveal that a halogen-bridged three-membered ring transition state is involved in the 1,2-Cl-/Br-atom shift, while the 1,2-I atom migration can be taken into account with an elimination/readdition mechanism. The migration ability was indicated to be ranked in the following order: I > Br > Cl.