72344-34-4

Basic information

• Product Name: 2-Phosphapropene, pentafluoro-
• Synonyms: 2-Phosphapropene, pentafluoro-
• CAS NO: 72344-34-4
• Molecular Formula: C₂F₅P
• Molecular Weight: 0
• Mol File: 72344-34-4.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Phosphapropene, pentafluoro-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Phosphapropene, pentafluoro-(72344-34-4)
• EPA Substance Registry System: 2-Phosphapropene, pentafluoro-(72344-34-4)

Safety Data

• Hazardous Substances Data: 72344-34-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C2F5P/c3-1(4)8-2(5,6)7

Upstream product

• 460-96-8 bis(trifluoromethyl)phosphine 
• 109-72-8 n-butyllithium 
• 17446-52-5 trimethylphosphinosilane 
• 99381-72-3 2,2-Difluoro-4,5-dimethyl-1-trifluoromethyl-1,2,3,6-tetrahydro-phosphinine 
• 99381-69-8 (1R,4S)-3,3-Difluoro-2-trifluoromethyl-2-phospha-bicyclo[2.2.1]hept-5-ene 
• 99381-70-1 (1S,4R)-3,3-Difluoro-2-trifluoromethyl-2-phospha-bicyclo[2.2.2]oct-5-ene 

Downstream Products

• 75-10-5 Difluoromethane 
• 75-46-7 trifluoromethan 
• 4669-85-6 Difluormethyl-phosphonigsaeure-dimethylester 
• 1571-80-8 Difluormethyl-trifluormethyl-phosphinigsaeure-methylester 
• 121-45-9 phosphorous acid trimethyl ester 
• 129138-27-8 Difluormethylen(diphenylphosphan)trifluormethylphosphan 
• 153367-55-6 ((CO)2Ni(PH(CF₃)CF₂PH(C(CH₃)3)))2 
• 129138-26-7 Difluormethylen(dicyclohexylphosphan)trifluormethylphosphan 
• 112151-67-4 (Z)-1,3,3,3-Tetrafluor-1-(N-methylanilino)-2-phospha-1-propen 

Relevant articles and documents

31P, 19F AND 1H NMR SPECTROSCOPIC STUDY OF THE REACTION OF BIS(TRIFLUOROMETHYL)PHOSPHINE AND SOLID KOH. SYNTHESIS OF THE PHOSPHAALKENE CF3P=CF2

The formation and subsequent reaction of the phosphaalkene CF3P=CF2 obtained via dehydrofluorination of (CF3)2PH with KOH pellets at room temperature has been studied by multinuclear NMR spectroscopy.

Reactive E=C (p-p)?-Systems, IV: Retro Diene Cleavage of Diels-Alder Adducts of the Phosphaalkene F3CP=CF2

Pyrolysis of the Diels-Alder adducts 2-4 yields F3CP=CF2 (1) and the corresponding dienes.For the thermal cleavage of 3 an alternative pathway in addition to the retro-diene reaction is observed, giving the new phosphetane F3CP-CF2 and C4H4 dimers.The enthalpy of the cyclo-reversion reaction of 2 as well as estimated bond energies for the phosphorus-carbon ?- and ?-bond have been determined from appearance potentials and thermochemical literature data.The products were characterized by mass and NMR spectra. - Keywords: Retro Diene Reactions, Phospha-Heterocycles, Mass Spectra, Thermochemical Data, NMR Spectra