726169-75-1Relevant articles and documents
Star-shaped fluorescent material based on carbazole asymmetric fused ring and preparation method and application of material
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Paragraph 0070-0073; 0081-0084, (2021/04/17)
The invention discloses a star-shaped fluorescent material based on a carbazole asymmetric fused ring as well as a preparation method and application of the star-shaped fluorescent material. The structural formula of the star-shaped fluorescent material based on the carbazole asymmetric fused ring is shown as a formula I. The star-shaped fluorescent material based on the carbazole asymmetric fused ring is a rigid conjugated molecule and has high thermal stability and high fluorescence quantum yield. The space structure can effectively inhibit fluorescence quenching; the star-shaped fluorescent material has high hole and electron injection and transmission capability and has the characteristic of bipolar transmission; the hybrid local charge transfer state characteristic is achieved, the high exciton utilization rate can be obtained, and high efficiency is achieved; the performance of the material is superior to that of a star-shaped fluorescent material based on a carbazole symmetric condensed ring; the star-shaped fluorescent materialhas good solubility, can be dissolved in a common organic solvent, is suitable for solution processing and ink-jet printing, can form a compact film, can be used for preparing a luminescent layer, and is beneficial to preparation of an electroluminescent device with excellent morphology; and when the materiel is used as a light-emitting layer of the device, the external quantum efficiency is 9% or above, and a wide development prospect is achieved.
Two Anthracene-Based Copolymers as the Hole-Transporting Materials for High-Performance Inverted (p-i-n) Perovskite Solar Cells
Tong, Tong,Tan, Chao,Keller, Tina,Li, Bobo,Zheng, Chaoyue,Scherf, Ullrich,Gao, Deqing,Huang, Wei
, p. 7407 - 7416 (2018/09/27)
Two anthracene-based copolymers, the thiophene-bridged carbazole-anthracene copolymer (abbreviated as PCBZANT) and the thiophene-bridged triphenylamine-anthracene copolymer (abbreviated as PTPAANT), have been developed as the hole-transporting materials (HTMs) for the inverted perovskite solar cells. They were thermally stable with decomposition temperatures of 435 and 420 °C. The High Occupied Molecular Orbitals (HOMO) of -5.15 and -5.24 eV of two copolymers facilitated the hole carriers transfer from the perovskite layer (CH3NH3PbI3, HOMO: -5.4 eV) in contrast to poly(3,4-ethylenedioxythiophene):polystyrenesulfonate (PEDOT:PSS, HOMO: -4.9 eV). The solar cell with PCBZANT (abbreviated as the PCBZANT device) showed the highest power conversion efficiency (PCE) of 15.50%, while the cell with PTPAANT (abbreviated as the PTPAANT device) showed the highest PCE of 14.52%, with increases of 36.2% and 27.6%, respectively, relative to the PEDOT:PSS device. The thorough analysis disclosed that the high performance was mainly ascribed to the enhanced open-circuit voltage (VOC) and short-circuit current density (JSC), being contributed from the efficient hole-carrier extraction, the high hole mobility of two copolymers, and the high-quality perovskite film with large crystal size and less defect. With strong absorption in the range of 350-500 nm, the polymers decreased the destruction of UV-radiation on the perovskite layer as UV-filters and improved the stability of the inverted cells.
Novel A-D-A type small molecules with β-alkynylated BODIPY flanks for bulk heterojunction solar cells
Liao, Junxu,Xu, Yongjun,Zhao, Hongbin,Zong, Qiao,Fang, Yutang
, p. 321 - 333 (2017/07/12)
A serial of novel A-D-A type small molecules with BODIPY linked through alkynyl with various electron donor units such as fluorene, carbazole, benzodithiophene and phenothiazine, namely F-BDP, C-BDP, B-BDP and P-BDP, respectively, were designed and synthe