72651-97-9

Basic information

• Product Name: 5-(2-furylmethyl)-2,2-dimethyl-1,3-dioxane-4,6-dione
• Synonyms: 5-(2-furylmethyl)-2,2-dimethyl-1,3-dioxane-4,6-dione;5-(furan-2-ylMethyl)-2,2-diMethyl-1,3-dioxane-4,6-dione
• CAS NO: 72651-97-9
• Molecular Formula: C₁₁H₁₂O₅
• Molecular Weight: 224.21
• Mol File: 72651-97-9.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 429.3°C at 760 mmHg
• Flash Point: 213.4°C
• Appearance: /
• Density: 1.238g/cm³
• Vapor Pressure: 1.42E-07mmHg at 25°C
• Refractive Index: 1.493
• CAS DataBase Reference: 5-(2-furylmethyl)-2,2-dimethyl-1,3-dioxane-4,6-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(2-furylmethyl)-2,2-dimethyl-1,3-dioxane-4,6-dione(72651-97-9)
• EPA Substance Registry System: 5-(2-furylmethyl)-2,2-dimethyl-1,3-dioxane-4,6-dione(72651-97-9)

Safety Data

• Hazardous Substances Data: 72651-97-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C11H12O5/c1-11(2)15-9(12)8(10(13)16-11)6-7-4-3-5-14-7/h3-5,8H,6H2,1-2H3

Upstream product

• 15875-49-7 5-furfurylidene-2,2-dimethyl-[1,3]dioxane-4,6-dione 
• 98-01-1 furfural 
• 2033-24-1 cycl-isopropylidene malonate 

Downstream Products

• 83540-62-9 5-Furan-2-ylmethyl-2,2-dimethyl-5-(4-nitro-benzyl)-[1,3]dioxane-4,6-dione 

Relevant articles and documents

Thermosetting resins with high fractions of free volume and inherently low dielectric constants

This work demonstrates a new class of thermosetting resins, based on Meldrum's acid (MA) derivatives, which have high fractions of free volume and inherently low k values of about 2.0 at 1 MHz. Thermal decomposition of the MA groups evolves CO2

A novel and green protocol for two-carbon homologation: A direct amino acid/K2CO3-catalyzed four-component reaction of aldehydes, active methylenes, Hantzsch esters and alkyl halides

A novel and green approach for the two-carbon homologation of aldehydes using amino acid catalysis has been developed and further extended to the generation of pharmaceutically active cyano-esters via four-component reactions in one-pot.

THE REDUCTIVE ALKYLATION OF MELDRUM'S ACID

Meldrum's acid can be reductively alkylated with borane*dimethylamine complex and aldehydes or ketones; borane*trimethylamine was used with cyclohexanone.