730-11-0

Basic information

• Product Name: Benzenamine, 4-methoxy-N-(4-nitrophenyl)-
• CAS NO: 730-11-0
• Molecular Formula: C13H12N2O3
• Molecular Weight: 244.25
• Mol File: 730-11-0.mol
• Article Data: 43

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-methoxy-N-(4-nitrophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-methoxy-N-(4-nitrophenyl)-(730-11-0)
• EPA Substance Registry System: Benzenamine, 4-methoxy-N-(4-nitrophenyl)-(730-11-0)

Safety Data

• Hazardous Substances Data: 730-11-0(Hazardous Substances Data)

Upstream product

• 104-94-9 4-methoxy-aniline 
• 586-78-7 para-nitrophenyl bromide 
• 100-25-4 para-dinitrobenzene 
• 699-19-4 4-methoxyphenylmagnesium chloride 
• 7440-44-0 pyrographite 
• 350-46-9 4-Fluoronitrobenzene 
• 100-00-5 4-chlorobenzonitrile 
• 16078-86-7 4-Hydroxy-4'-nitrodiphenylamine 
• 123-30-8 4-amino-phenol 
• 636-98-6 p-nitrobenzene iodide 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 100-01-6 4-nitro-aniline 
• 100-32-3 di(p-nitrophenyl) disulfide 
• 5720-07-0 4-methoxyphenylboronic acid 

Downstream Products

• 1220986-88-8 C₁₅H₁₃ClN₂O₄ 
• 1220986-89-9 C₁₅H₁₃BrN₂O₄ 

Relevant articles and documents

Design and synthesis of hyperbranched polyimide containing multi-triphenylamine moieties for memory devices

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Cu-Catalyzed Cross-Coupling of Nitroarenes with Aryl Boronic Acids to Construct Diarylamines

The development and study of a simple copper-catalyzed reaction of nitroarenes with aryl boronic acids to form diarylamines that uses phenyl silane as the stoichiometric terminal reductant is described. This cross-coupling reaction requires as little as 2 mol % of CuX and 4 mol % of diphosphine for success and tolerates a broad range of functional groups on either the nitroarene or the aryl boronic acid to afford the amine in good yield. Mechanistic investigations established that the cross-coupling reaction proceeds via a nitrosoarene intermediate and that copper is required to catalyze both the deoxygenation of the nitroarene to afford the nitrosoarene and C-NAr bond formation of the nitrosoarene with the aryl boronic acid.