75-25-2Relevant articles and documents
Carothers,Jacobson,Berchet
, p. 4667 (1933)
Compounds and methods for the reduction of halogenated hydrocarbons
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Page/Page column 21-22, (2017/12/27)
The present application relates to methods for the reduction of halogenated hydrocarbons using compounds of Formula (I): wherein the reduction of the halogenated compounds is carried out, for example, under ambient conditions without the need for a transition metal containing co-factor. The present application also relates to methods of recovering precious metals using compounds of Formula (I) that are absorbed onto a support material.
Bromination of hydrocarbons with CBr4, initiated by light-emitting diode irradiation
Nishina, Yuta,Ohtani, Bunsho,Kikushima, Kotaro
, p. 1663 - 1667 (2013/10/22)
The bromination of hydrocarbons with CBr4 as a bromine source, induced by light-emitting diode (LED) irradiation, has been developed. Monobromides were synthesized with high efficiency without the need for any additives, catalysts, heating, or inert conditions. Action and absorption spectra suggest that CBr4 absorbs light to give active species for the bromination. The generation of CHBr3 was confirmed by NMR spectroscopy and GC-MS spectrometry analysis, indicating that the present bromination involves the homolytic cleavage of a C-Br bond in CBr4 followed by radical abstraction of a hydrogen atom from a hydrocarbon.