7570-97-0Relevant articles and documents
Synthesis of benzyl thioether derivatives via N-heterocyclic carbene palladium(II)-catalyzed cross coupling of benzylammonium salts with thiophenols
Wang, Tao,Guo, Jiarui,Xu, Yongli,Wang, Xiaobo,Wang, Yan,Feng, Dandan,Liu, Lantao
, (2021/12/01)
A new route to benzyl thioether derivatives has been developed via the N-heterocyclic carbene palladium(II)-catalyzed cross coupling of benzylammonium salts with thiophenols. Under the optimal conditions, different benzylammonium salts could be well toler
Transition-Metal-Free and Base-Promoted Carbon-Heteroatom Bond Formation via C-N Cleavage of Benzyl Ammonium Salts
Liu, Long,Tang, Yuanyuan,Wang, Kunyu,Huang, Tianzeng,Chen, Tieqiao
, p. 4159 - 4170 (2021/03/09)
A facile and general method for constructing carbon-heteroatom (C-P, C-O, C-S, and C-N) bonds via C-N cleavage of benzyl ammonium salts under transition-metal-free conditions was reported. The combination of t-BuOK and 18-crown-6 enabled a wide range of substituted benzyl ammonium salts to couple readily with different kinds of heteroatom nucleophiles, i.e. hydrogen phosphoryl compounds, alcohols, thiols, and amines. Good functional group tolerance was demonstrated. The scale-up reaction and one-pot synthesis were also successfully performed.
Synthesis and characterization of Pd(II) complexes bearing NS, CS, SNS and SCS ligands. Evaluation of their microwave assisted catalytic activity in C–C coupling reactions
Aguilar-Castillo, Bethsy A.,Gabriel Flores-Rojas, G.,González-Sebastián, Lucero,Hernández-Ortega, Simón,Morales-Morales, David,Reyes-Martínez, Reyna
, (2020/05/29)
A series of coordination (Pd-NS, Pd-SNS, Pd-SNS-O) and organometallic (Pd-C and Pd-SCS) Pd(II) complexes supported by bidentate and tridentate ligands featuring sulphur moieties have been prepared. All ligands and their palladium complexes were fully char
