76358-92-4

Basic information

• Product Name: Pyridine, 2-[(phenylseleno)methyl]-
• CAS NO: 76358-92-4
• Molecular Formula: C12H11NSe
• Molecular Weight: 248.186
• Mol File: 76358-92-4.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Pyridine, 2-[(phenylseleno)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Pyridine, 2-[(phenylseleno)methyl]-(76358-92-4)
• EPA Substance Registry System: Pyridine, 2-[(phenylseleno)methyl]-(76358-92-4)

Safety Data

• Hazardous Substances Data: 76358-92-4(Hazardous Substances Data)

Upstream product

• 586-98-1 2-Hydroxymethylpyridine 
• 71098-88-9 N-phenylselanylphthalimide 
• 2179-79-5 phenyl selenocyanate 
• 5707-04-0 Phenylselenyl chloride 
• 109-06-8 α-picoline 
• 1666-13-3 diphenyl diselenide 
• 31106-82-8 2-(bromomethyl)pyridine hydrobromide 
• 4377-33-7 2-chloromethylpyridine 
• 43071-19-8 2-[(Dimethylamino)methyl]pyridine 
• 591-50-4 iodobenzene 
• 106966-98-7 potassium 2-(pyridin-2-yl)acetate 

Downstream Products

• 4916-40-9 1,2-bis(pyridin-2-yl)ethane 
• 1666-13-3 diphenyl diselenide 
• 18255-05-5 benzyl phenyl selenide 
• 78808-34-1 9-anthrylmethyl phenyl selenide 
• 404361-95-1 Pd(0)(η2-fumaronitrile)(C5H4NCH2SeC6H5) 
• 1206594-85-5 PdCl₂(2-phenylselenomethylpyridine) 
• 1268397-94-9 N-methyl 2-(phenylselenomethyl)pyridinium triflate 
• 1370620-98-6 ((C₅(CH₃)5)IrCl(NC₅H₄CH₂SeC₆H₅))⁽¹⁺⁾*PF₆^(1-)=((C₅(CH₃)5)IrCl(NC₅H₄CH₂SeC₆H₅))PF₆ 
• 1441253-24-2 [ruthenium(II)(η⁶-benzene)(chloride)(NC5H4CH2SeC6H5)](hexafluorophosphate) 

Relevant articles and documents

Transition-metal-free decarboxylative thiolation of stable aliphatic carboxylates

A transition-metal-free decarboxylative thiolation protocol is reported in which primary, secondary, tertiary (hetero)aryl acetates and α-CN substituted acetates undergo the decarboxylative thiolation smoothly, to deliver a variety of functionalized aryl alkyl sulfides in moderate to excellent yields. Aryl diselenides are also amenable substrates for construction of C-Se bonds under the simple and mild reaction conditions. Moreover, the protocol is successfully applied to the late-stage modification of pharmaceutical carboxylates with satisfactory chemoselectivity and functional-group compatibility. This journal is

Transition metal-free coupling reactions of benzylic trimethylammonium salts with di(hetero)aryl disulfides and diselenides

A new protocol was developed to synthesize (enantioenriched) thioethers and selenoethers from (chiral) benzylic trimethylammonium salts and di(hetero)aryl disulfides or diselenides. These syntheses were promoted by the presence of weak base and did not require the use of any transition metal, and resulted in the target products with good to excellent yields (72-94%). Using quaternary ammonium salts synthesized from enantiomerically enriched amines led to highly enantiopure benzylic thioethers and selenoethers (94-99% ee) with configurations reversed from those of their enantioenriched quaternary ammonium salts. This journal is

Metal-free sp3 C-H functionalization: A novel approach for the syntheses of selenide ethers and thioesters from methyl arenes

A DTBP-promoted metal-free and solvent-free formation of C-Se and C-S bonds through sp3 C-H functionalization of methyl arenes with diselenides and disulfides is described. the Partner Organisations 2014.