76620-28-5

Basic information

• Product Name: 3-Pentyn-1-one, 1-phenyl-
• CAS NO: 76620-28-5
• Molecular Formula: C11H10O
• Molecular Weight: 158.2
• Mol File: 76620-28-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-Pentyn-1-one, 1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Pentyn-1-one, 1-phenyl-(76620-28-5)
• EPA Substance Registry System: 3-Pentyn-1-one, 1-phenyl-(76620-28-5)

Safety Data

• Hazardous Substances Data: 76620-28-5(Hazardous Substances Data)

Upstream product

• 96-09-3 styrene oxide 
• 74-99-7 prop-1-yne 
• 4885-09-0 1-phenyl-3-pentyn-1-ol 
• 84066-64-8 1-phenyl-1-(2-butynyl)dithiane 
• 611-74-5 N,N-dimethylbenzamide 
• 613-90-1 benzoyl cyanide 
• 3355-28-0 1-Bromo-2-butyne 
• 5425-44-5 2-Phenyl-[1,3]dithiane 
• 84066-63-7 2-(2-propynyl)-2-phenyl-1,3-dithiane 
• 79-03-8 propionyl chloride 
• 20913-05-7 (Benzoylmethylene)triphenylphosphorane 
• 100-52-7 benzaldehyde 

Downstream Products

• 61752-45-2 Z-1-phenylpent-3-en-1-one 
• 76620-27-4 cis-1-phenyl-3-penten-1-one N-tosylhydrazone 
• 76620-29-6 ((Z)-1-Diazo-pent-3-enyl)-benzene 
• 76633-73-3 exo-6-methyl-3-phenyl-1,2-diazabicyclo<3.1.0>hex-2-ene 
• 76620-30-9 endo-3-phenyl-6-methyl-1,2-diazabicyclo<3.1.0>hex-3-ene 
• 76620-30-9 endo-3-phenyl-6-methyl-1,2-diazabicyclo<3.1.0>hex-2-ene 
• 76620-30-9 exo-3-phenyl-6-methyl-1,2-diazabicyclo<3.1.0>hex-2-ene 

Relevant articles and documents

Formal metal-free γ-arylation of 1,3-dicarbonyl compounds: Via an isomerisation/1,4-addition/[3,3]-sigmatropic rearrangement sequence

A metal-free redox arylation of alkynes with sulfoxides has been developed to provide unconventional access to diverse γ-arylated 1,3-dicarbonyl compounds in an atom-economical manner. Mechanistic studies suggest that a conjugated allenone intermediate was generated in situ, which solves the problem of reactivity and regioselectivity of unsymmetrical dialkyl-substituted internal alkynes and enables the functionalisation of a broad range of substrates bearing electron-withdrawing functional groups. The resulting arylated 1,3-dicarbonyl compounds are versatile and useful building blocks for further functionalisation. This journal is

Indium-mediated highly regioselective reaction of prop-2-ynyl bromides with acyl cyanides in aqueous media: A convenient synthesis of allenic and propargylic ketones

Indium-mediated reaction of acyl cyanides 1 with prop-2-ynyl bromides 2 in aqueous media occurs regioselectively to afford either allenic 3 or propargylic ketones 4 depending on the γ-substituent of the prop-2-ynyl bromide under the mild conditions.