77367-27-2Relevant articles and documents
Silver-mediated oxidative aliphatic C-H trifluoromethylthiolation
Guo, Shuo,Zhang, Xiaofei,Tang, Pingping
, p. 4065 - 4069 (2015)
The first example of a practical and direct trifluoromethylthiolation reaction of unactivated aliphatic C-H bonds employs a silver-based reagent. The reaction is operationally simple, scalable, and proceeds under aqueous conditions in air. Furthermore, its broad scope and good functional-group compatibility were demonstrated by applying this method to the selective trifluoromethylthiolation of natural products and natural-product derivatives.
