77929-17-0

Basic information

• Product Name: 2-phenyl-1,3,2-oxazaphosphole-2-oxide
• Synonyms: 2-phenyl-1,3,2-oxazaphosphole-2-oxide
• CAS NO: 77929-17-0
• Molecular Weight: 223.211
• Mol File: 77929-17-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-phenyl-1,3,2-oxazaphosphole-2-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-phenyl-1,3,2-oxazaphosphole-2-oxide(77929-17-0)
• EPA Substance Registry System: 2-phenyl-1,3,2-oxazaphosphole-2-oxide(77929-17-0)

Safety Data

• Hazardous Substances Data: 77929-17-0(Hazardous Substances Data)

Upstream product

• 824-72-6 P,P-dichlorophenylphosphine oxide 
• 23356-96-9 (S)-1-Pyrrolidin-2-yl-methanol 

Downstream Products

• 65665-33-0 (+)-(R)_p Methyl ethylphenylphosphinate 
• 78177-46-5 (R)-(2-Hydroxymethyl-pyrrolidin-1-yl)-phenyl-phosphinic acid methyl ester 
• 77929-21-6 (+)-(R)_p Methyl allylphenylphosphinate 
• 61733-60-6 (R)-O-ethyl O-methyl phenylphosphonothioate 
• 77929-23-8 methyl (S)-(2-methoxyphenyl)(phenyl)phosphinate 
• 6389-79-3 (+)-(R)_p methyl methylphenylphosphinate 

Relevant articles and documents

Enantioselective reduction of ketones by borane catalysed by oxazaphospholidine oxides

New enantioselective catalysts for the asymmetric reduction of ketones by borane are described. Easily prepared by oxidation of chiral oxazaphospholidines, these compounds increase sensitively the reduction rate of numerous ketones and induce ee's up to 94% in the case of the 2-chloroacetophenone.

New chiral phosphinamide catalysts for highly enantioselective reduction of ketones

A novel class of recoverable and highly stable phosphinamide catalysts for the asymmetric reduction of ketones by borane is described. Enantiomeric excesses of up to 92% have been obtained using 10 mol% of the optimum catalyst.