82234-81-9

Basic information

• Product Name: (non-2-en-1-ylsulfonyl)benzene
• Synonyms: (non-2-en-1-ylsulfonyl)benzene
• CAS NO: 82234-81-9
• Molecular Weight: 266.404
• Mol File: 82234-81-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (non-2-en-1-ylsulfonyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (non-2-en-1-ylsulfonyl)benzene(82234-81-9)
• EPA Substance Registry System: (non-2-en-1-ylsulfonyl)benzene(82234-81-9)

Safety Data

• Hazardous Substances Data: 82234-81-9(Hazardous Substances Data)

Upstream product

• 629-05-0 n-octyne 
• 7205-98-3 chloromethyl phenyl sulfone 
• 124-13-0 Octanal 
• 112863-56-6 (E)-(non-1-en-1-ylsulfonyl)benzene 
• 56069-39-7 diethyl phenylsulfonylmethylphosphonate 
• 38066-16-9 diethyl [(phenylthio)methyl]phosphonate 
• 1397699-21-6 C₉H₁₉N 
• 873-55-2 sodium benzenesulfonate 
• 3406-02-8 bis(phenylsulfonyl)methane 
• 82234-72-8 C₂₁H₂₆O₄S₂ 

Downstream Products

• 6434-78-2 2-nonene 

Relevant articles and documents

Carbenoid insertion into alkenylzirconocenes - A convergent synthesis of functionalised allylmetallics

Insertion of lithium alkylcarbenoids RC(A)LiX, A = CN, P(O)(OEt)2, SO2Ph, OMe into alkenylzirconocene chlorides derived by hydrozirconation of terminal alkynes affords functionalised allylzirconium reagents which may be further elaborated. (C) 2000 Elsevuer Science Ltd.

Direct substitution of primary allylic amines with sulfinate salts

The NH2 group in primary allylic amines was substituted directly by sulfinate salts with excellent regio- and stereoselectivities. In the presence of 0.1 mol % [Pd(allyl)Cl]2, 0.4 mol % 1,4- bis(diphenylphosphino)butane (dppb), and excess boric acid, a range of α-unbranched primary allylic amines were smoothly substituted with sodium sulfinates in an α-selective fashion to give structurally diverse allylic sulfones in good to excellent yields with exclusive E selectivity. Replacing dppb with 1,1′-bi-2-naphthol (BINOL) allowed unsymmetric α-chiral primary allylic amines to be transformed into the corresponding allylic sulfones in good to excellent yields with excellent retention of ee. Importantly, the reaction complements known asymmetric methods in substrate scope via its unique ability to provide α-chiral allylic sulfones with high optical purity starting from unsymmetric allylic electrophiles.