82532-09-0Relevant articles and documents
Reactions involving Transition Metals. Part 18.1 Reactions of Transition-metal Complexes with peroxycarboxylic Acids, Diacyl Peroxides, and t-Butyl Peroxybenzoate
Bird, Christopher,Booth, Brian L.,Haszeldine, Robert N.,Neuss, Geoffrey R. H.,Smith, Myles A.,Flood, Andrew
, p. 1109 - 1116 (2007/10/02)
The iridium(I) complexes 1)(L2)2> (L1 = CO or N2) react with peroxycarboxylic acid, RCO3H, to give the carboxylato-complexes 2)2> (X = Cl, R = 3-ClC6H4, L2 = PPh3, PPh2Me, or AsPh3; X = Cl, R = Ph, L2 = PPh3 or AsPh3; X = Cl, R = Me, L2 = PPh3; X = BR, R = 3-ClC6H4, L2 = PPh3) with evolution of carbon dioxide; the compounds (X = Cl, L2 = PPh3, R = Me, Ph, or 3-ClC6H4) have also been obtained from and diacyl peroxides.The iodo complex behaves anomalously giving with RCO3H (R = Ph or 3-ClC6H4), and a mixture of and with dibenzoyl peroxide.Diacyl peroxides, (RCO2)2, react with to give the complexes (R = Ph or 3-ClCH64) in high yields, and the compound where R = Ph rather than the expected is formed under similar conditions with acetyl peroxybenzoate.The palladium(0) complexes (L = PPh3 or 1/2 Ph2PCH2CH2PPh2) react to form with dibenzoyl peroxide at room temperature, but (M = Pt or Pd) and do not react under these conditions.Similarly, there is no reaction between and the peroxy-ester ButO2C(O)Ph at room temperature, but and give and respectively as the only metal-containing products.
