83395-39-5 Usage
Description
1H-Imidazole-1-carboxylicacid,2-propenylester(9CI), also known as allyl 1H-imidazole-1-carboxylate, is an organic compound that features an imidazole ring with a carboxylic acid group and a propenyl ester side chain. This molecule is characterized by its ability to form various chemical reactions and has potential applications in different industries due to its unique structure and reactivity.
Uses
Used in Chemical Synthesis Industry:
1H-Imidazole-1-carboxylicacid,2-propenylester(9CI) is used as a reagent for the preparation of allyl enol carbonate derivatives. It is achieved through a reaction with ketone enolates and boron trifluoride etherate, which allows for the synthesis of a variety of complex organic molecules with potential applications in pharmaceuticals, agrochemicals, and other specialty chemicals.
Used in Organic Chemistry Research:
In the field of organic chemistry, 1H-Imidazole-1-carboxylicacid,2-propenylester(9CI) serves as a valuable intermediate for the acylation of a mixture of primary and secondary alcohols. This process is crucial for the development of new synthetic routes and methodologies, as well as for the synthesis of bioactive compounds and novel materials.
Overall, 1H-Imidazole-1-carboxylicacid,2-propenylester(9CI) is a versatile compound with applications in chemical synthesis and research, making it an important molecule for the development of new chemical entities and processes.
Check Digit Verification of cas no
The CAS Registry Mumber 83395-39-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,3,3,9 and 5 respectively; the second part has 2 digits, 3 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 83395-39:
(7*8)+(6*3)+(5*3)+(4*9)+(3*5)+(2*3)+(1*9)=155
155 % 10 = 5
So 83395-39-5 is a valid CAS Registry Number.
83395-39-5Relevant articles and documents
Design and Synthesis of Cyclic Mismatch-Binding Ligands (CMBLs) with Variable Linkers by Ring-Closing Metathesis and their Photophysical and DNA Repeat Binding Properties
Mukherjee, Sanjukta,Dohno, Chikara,Nakatani, Kazuhiko
, p. 11385 - 11396 (2017)
Cyclophane-containing bis(2-amino-1,8-naphthyridine) moieties attached to variable linkers at the C2-position (linker B) were synthesized as cyclic mismatch-binding ligands (CMBLs). Ring-closing metathesis (RCM) is used as a key step for the introduction
Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Dihydroquinolinones
Trost, Barry M.,Nagaraju, Anugula,Wang, Feijun,Zuo, Zhijun,Xu, Jiayi,Hull, Kami L.
supporting information, (2019/03/19)
A palladium-catalyzed decarboxylative asymmetric allylic alkylation (Pd-DAAA) of benzo-fused and non-benzo-fused δ-valerolactams is disclosed. This methodology gives access to chiral lactams bearing C3-quaternary stereocenters, which are central to many n
Studies on the enantioselective synthesis of carbazolones as intermediates in aspidosperma and kopsia alkaloid synthesis
Gartshore, Christopher J.,Lupton, David W.
, p. 882 - 890 (2013/09/12)
Two strategies for the assembly of homochiral carbazolones have been investigated. The first exploited desymmetrisation of 1,3-cyclohexadione derivatives however this failed to deliver satisfactory outcomes. An orthogonal route exploiting palladium catalysed decarboxylative allylation of racemic carbazolone β-ketoesters has been developed. Herein we report full details on the development of this reaction and clarify apparent discrepancies between our preliminary reports and those of Shao.