83816-48-2

Basic information

• Product Name: (-)-1-p-methoxyphenyl-3-butyn-1-ol
• CAS NO: 83816-48-2
• Molecular Weight: 176.215
• Mol File: 83816-48-2.mol
• Article Data: 55

Chemical Properties

• CAS DataBase Reference: (-)-1-p-methoxyphenyl-3-butyn-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-1-p-methoxyphenyl-3-butyn-1-ol(83816-48-2)
• EPA Substance Registry System: (-)-1-p-methoxyphenyl-3-butyn-1-ol(83816-48-2)

Safety Data

• Hazardous Substances Data: 83816-48-2(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 106-96-7 propargyl bromide 
• 463-49-0 1,2-propanediene 
• 1337935-39-3 4,4,5,5-tetramethyl-2-(prop-2-yn-1-yl)-1,3,2-dioxaborolane 
• 18295-60-8 propargyl magnesium bromide 
• 13361-64-3 trimethyl(propargyl)silane 
• 70557-99-2 2-(iodomethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 4301-14-8 acetylenemagnesium bromide 
• 865350-17-0 4,4,5,5-tetramethyl-2-(propa-1,2-dien-1-yl)-1,3,2-dioxaborolane 
• 1020850-71-8 trifluoromethanesulfonic acid 2-(4-methoxyphenyl)-6-oxo-3,6-dihydro-2H-pyran-4-yl ester 
• 75-16-1 methylmagnesium bromide 
• 33415-30-4 trichloro(propa-1,2-dienyl)silane 
• 2186-92-7 p-Anisaldehyde dimethyl acetal 
• 53915-69-8 allenyltributylstannane 

Downstream Products

• 194095-61-9 (5E)-6-chloro-1-(p-methoxyphenyl)hex-5-en-3-yn-1-ol 
• 362707-18-4 5-(4-methoxyphenyl)dihydrofuran-3-one 
• 1332524-44-3 3-cyano-2,6-dimethyl-1-(4-methoxybenzoyl)-4-(4-methoxyphenyl)benzene 
• 1332524-79-4 (Z)-5-(4-methoxyphenyl)-2,3-dimethyl-5-oxopent-2-enenitrile 
• 1332524-81-8 (E)-5-(4-methoxyphenyl)-2,3-dimethyl-5-oxopent-2-enenitrile 
• 1332524-96-5 (E)-2-benzyl-5-(4-methoxyphenyl)-3-methyl-5-oxopent-2-enenitrile 
• 1332524-94-3 (Z)-2-benzyl-5-(4-methoxyphenyl)-3-methyl-5-oxopent-2-enenitrile 
• 1379060-14-6 C₁₁H₁₁BrO₂ 
• 1250880-92-2 C₁₁H₁₀O₂ 
• 17113-31-4 2-(4-methoxyphenyl)furan 
• 196952-70-2 1-(4-methoxyphenyl)buta-2,3-dien-1-one 

Relevant articles and documents

Stereodivergent Palladium- And Rhodium-Catalyzed Intramolecular Addition of Tosylureas to Allenes: Diastereoselective Synthesis of Tetrahydropyrimidinones

The intramolecular addition of tosylureas to allenes is highly syn-/anti-diastereoselective when employing a palladium or rhodium-based catalytic system and affords 1,3-cyclic ureas. Under palladium catalysis a range of thermodynamic anti-tetrahydropyrimi

Dibrominative Spirocyclization of 2-Butynolyl Anilides: Synthesis of gem-Dibromospirocyclic Benzo[ d][1,3]oxazines and Their Application in the Synthesis of 4 H-Furo[3,2- b]indoles

The combination of catalytic aqueous hydrochloric acid (HCl) and N-bromosuccinimide (NBS) generated electrophilic bromine monochloride (BrCl), which readily induced spiroannulation of 2-alkynolyl anilides (n = 1-3) to form gem-dibromospirocyclic benzo[d][

Gold-Catalyzed Tandem Oxidative Coupling Reaction between β-Ketoallenes and Electron-Rich Arenes to 2-Furylmethylarenes

A tandem oxidative coupling reaction of β-ketoallenes and arenes was developed, which leads to the formation of 2-furylmethylarenes using AuCl3 and phenyliodine diacetate. The AuIII salt catalyzed the cyclization of β-ketoallenes to form a 2-furylmethyl gold intermediate, and the subsequent C-H functionalization of arenes proceeded smoothly. During the oxidative coupling, nucleophilic additions occurred at the center and terminal carbon atoms of the allene moiety to form C-O and C-C bonds.