84653-73-6Relevant articles and documents
1,2-dicarbonyl compound and synthesis method thereof
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Paragraph 0155; 0148-0151, (2019/10/01)
The invention discloses a method for synthesizing a 1,2-dicarbonyl compound (1,2-dicarbonylamide or alpha-diketone compound), wherein 1,2-dicarbonyl thioester compounds used as 1,2-dicarbonyl reagentsreact with amine compounds or boric anhydride compounds under appropriate conditions to respectively synthesize a series of 1,2-dicarbonyl compounds. According to the present invention, the 1,2-dicarbonyl compound is obtained by using the stable 1,2-dicarbonyl thioester compound as the dicarbonylation reagent through one-step construction under mild conditions, such that the disadvantage that thetraditional method uses the unstable alpha-carbonyl acyl chloride to synthesize the 1,2-dicarbonyl compound is avoided.
Stereochimie de la reduction electrochimique d'α-cetoamides optiquement actives II. Electroreduction de benzoylformamides derives de la S(-)-proline
Boulmedais, Ali,Jubault, Michel,Tallec, Andre
, p. 185 - 191 (2007/10/02)
Electrochemical reduction of benzoylformamides derived from S-(-)-proline has been carried out at a mercury cathode in a buffered hydroalcoholic medium; quantitative formation of a mixture of the two epimers of the corresponding mandelamides is observed.D