851909-01-8

Basic information

• Product Name: N-(N-(Fmoc)-L-allylglycyl)-N-(2,4-dimethoxybenzyl)-L-homoallylglycine methyl ester
• Synonyms: N-(N-(Fmoc)-L-allylglycyl)-N-(2,4-dimethoxybenzyl)-L-homoallylglycine methyl ester
• CAS NO: 851909-01-8
• Molecular Weight: 612.723
• Mol File: 851909-01-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-(N-(Fmoc)-L-allylglycyl)-N-(2,4-dimethoxybenzyl)-L-homoallylglycine methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: N-(N-(Fmoc)-L-allylglycyl)-N-(2,4-dimethoxybenzyl)-L-homoallylglycine methyl ester(851909-01-8)
• EPA Substance Registry System: N-(N-(Fmoc)-L-allylglycyl)-N-(2,4-dimethoxybenzyl)-L-homoallylglycine methyl ester(851909-01-8)

Safety Data

• Hazardous Substances Data: 851909-01-8(Hazardous Substances Data)

Upstream product

• 851909-11-0 methyl (2S)-2-[(2,4-dimethoxybenzyl)amino]hex-5-enoate 
• 146549-21-5 2-(9H-fluoren-9-ylmethoxycarbonylamino)-pent-4-enoic acid 
• 613-45-6 2,4-Dimethoxybenzaldehyde 
• 410098-01-0 (2S)-2-aminohex-5-enoic acid methyl ester 
• 659726-50-8 tert-butyl (2S)-2-[N-(9-phenylfluoren-9-yl)amino]pent-4-enoate 
• 92136-57-7 (S)-2-tert-butoxycarbonylamino-hex-5-enoic acid methyl ester 

Downstream Products

• 851908-94-6 methyl (E,3S,9S)-3-N-(Fmoc)amino-1-(2,4-dimethoxybenzyl)-2-oxo-2,3,4,7,8,9-hexahydro-1H-azonine-9-carboxylate 
• 903520-19-4 1-(2,4-dimethoxy-benzyl)-8-(9H-fluoren-9-ylmethoxycarbonylamino)-9-oxo-2,3,4,7,8,9-hexahydro-1H-azonine-2-carboxylic acid methyl ester 

Relevant articles and documents

From macrocycle dipeptide lactams to azabicyclo[X.Y.0]alkanone amino acids: A transannular cyclization route for peptide mimic synthesis

Macrocyclic and fused bicyclic dipeptides are complementary motifs for mimicry of different types of β-turn geometry. Macrocyclic dipeptide mimics have served as precursors for the synthesis of their bicyclic counterparts using electrophilic transannular

Systematic study of the synthesis of macrocyclic dipeptide β-turn mimics possessing 8-, 9-, and 10- membered rings by ring-closing metathesis

A systematic study was performed to establish general synthesis protocols for forming enantiomerically pure macrocyclic dipeptide lactams. Focusing on macrocycles of 8-, 9-, and 10-membered rings, effective syntheses were achieved by a sequence featuring