85278-15-5Relevant articles and documents
Copper-catalyzed allylic hydroxyamination and amination of alkenes with Boc-hydroxylamine
Kalita, Biswajit,Nicholas, Kenneth M.
, p. 1451 - 1453 (2005)
Olefins react regioselectively with Boc-NHOH in the presence of Cu(I,II) salts to produce allyl-N(OH)(Boc) derivatives, apparently via the intermediacy of Boc-NO; yields and rates are dramatically improved by the addition of H 2O2. The corresponding allylamine derivatives, allyl-NH(Boc), are formed selectively from Boc-NHOH/olefin with CuBr/P(OEt) 3.