86014-07-5

Basic information

• Product Name: (4-(benzyloxy)but-1-en-2-yl)dimethyl(phenyl)silane
• Synonyms: (4-(benzyloxy)but-1-en-2-yl)dimethyl(phenyl)silane
• CAS NO: 86014-07-5
• Molecular Weight: 296.484
• Mol File: 86014-07-5.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (4-(benzyloxy)but-1-en-2-yl)dimethyl(phenyl)silane(CAS DataBase Reference)
• NIST Chemistry Reference: (4-(benzyloxy)but-1-en-2-yl)dimethyl(phenyl)silane(86014-07-5)
• EPA Substance Registry System: (4-(benzyloxy)but-1-en-2-yl)dimethyl(phenyl)silane(86014-07-5)

Safety Data

• Hazardous Substances Data: 86014-07-5(Hazardous Substances Data)

Upstream product

• 22273-77-4 ((but-3-yn-1-yloxy)methyl)benzene 
• 3839-31-4 dimethyl(phenyl)silyllithium 
• 765-03-7 1-dodecyne 
• 185990-03-8 dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 

Relevant articles and documents

Copper-catalyzed highly regioselective silylcupration of terminal alkynes to form α-vinylsilanes

A highly regioselective synthesis of branched vinylsilanes through silicon-copper additions to terminal alkynes catalyzed by copper(I) was developed using methanol as additive. The corresponding vinylsilanes were obtained with excellent branched to linear selectivity of up to 99/1 in good yields.

TRANSITION-METAL CATALYZED SILYLZINCATION AND SILYLALUMINATION OF ACETYLENIC COMPOUNDS

Dialkyl(dimethylphenylsilyl)zinclithium and trialkyl(dimethylphenylsilyl)aluminiumlithium add effectively to internal acetylenes as well as terminal ones in the presence of transition-metal catalysts to provide vinylsilanes with high stereo- and regiosele

COPPER CATALYZED SILYLZINCATION OF ACETYLENES

Dialkyl(dimethylphenylsilyl)zinclithium adds effectively to internal acetylenes as well terminal acetylenes in the presence of CuCN catalyst.